(i-Pr)2InCl | 123241-18-9

• 英文名称: (i-Pr)2InCl
• CAS: 123241-18-9
• 化学式: C₁₂H₂₈Cl₂In₂
• 分子量: 472.9
• InChiKey: KMHJAVUTKCIPMT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,2,6,6-四甲基哌啶 、 (i-Pr)2InCl 在 正丁基锂 作用下， 以 正己烷 、 正戊烷 为溶剂， 以44%的产率得到di-isopropyl(2,2,6,6-tetramethylpiperidino)indium(III)
  参考文献：
  名称：

  Synthesis and characterization of new monomeric dialkylindium amides

  摘要：

  A series of organoindium amido compounds have been prepared for use as dopants in the organometallic vapor phase epitaxy (OMVPE) of II-VI semiconductor materials. Thus, reaction of tBu2InCl or iPr2InCl with the appropriate lithium or sodium dialkyiamide afforded compounds of the type R2InNR2' (where R = (t)Bu, (i)Pr, and R' = Me, (i)Pr, SiMe3). Similarly, reaction of the N-lithiated derivative of NCMe2(CH2)3CMe2 gave iPr2InNCMe2(CH)3CMe2. All of the compounds are monomeric liquids, except for the compound where R = (t)Bu, R' = Me, which is a dimeric solid. The compounds have been characterized by H-1 and C-13 NMR, IR, molecular weight determination, and elemental analysis. In addition, properties relevant to the OMVPE process such as volatility and photosensitivity are presented and evaluated.

  DOI：

  10.1016/0022-328x(93)83312-j
• 作为产物：
  描述：

  氯化铟 、 triisopropyl indium 以 甲苯 为溶剂， 以97%的产率得到(i-Pr)2InCl
  参考文献：
  名称：

  Neumueller, Bernhard, Chemische Berichte, 1989, vol. 122, p. 2283 - 2287

  摘要：

  DOI：