(μ-H)Os3(CO)10(μ-η(2)-CH2C3H4NS) | 288265-00-9

• 英文名称: (μ-H)Os3(CO)10(μ-η(2)-CH2C3H4NS)
• CAS: 288265-00-9
• 化学式: C₁₄H₇NO₁₀Os₃S
• 分子量: 951.876
• InChiKey: OXHNFWBZKTWPBW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (μ-H)Os3(CO)10(μ-η(2)-CH2C3H4NS) 以 正庚烷 为溶剂， 以45%的产率得到(μ-H)2Os3(CO)9(μ(3)-eta.(2)-CH2C3H4NS)
  参考文献：
  名称：

  Metallation of 2-methyl-2-thiazoline at a triosmium cluster: X-ray structure of [(μ-H)Os3(CO)10(μ-η2-CH2)]

  摘要：

  The reaction of [Os-3(CO)(10)(MeCN)(2)] with 2-methyl-2-thiazoline at ambient temperature results in the C-H activation of the methyl substituent of the heterocyclic ligand and this gives the new compound [(mu-H)Os-3(CO)(10)(mu-eta(2)-CH2C=NCH2CH2S] (8) in 55% yield. Compound 8 undergoes decarbonylation and a further C-H bond activation by thermolysis at 98 degrees C or by treatment with trimethylamine-N-oxide to give the dihydrido cluster [(mu-H)(2)Os-3(CO)(9)(mu-eta(2)-CHC=NCH2CH2S] (9) in 45% yield. Both complexes have been characterized by elemental analyses, IR and H-1 NMR spectroscopy, together with X-ray crystallography for 8. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00354-5
• 作为产物：
  描述：

  2-甲基-2-噻唑啉 、 bis(acetonitrile)decacarbonyltriosmium 以 二氯甲烷 为溶剂， 以55%的产率得到(μ-H)Os3(CO)10(μ-η(2)-CH2C3H4NS)
  参考文献：
  名称：

  Metallation of 2-methyl-2-thiazoline at a triosmium cluster: X-ray structure of [(μ-H)Os3(CO)10(μ-η2-CH2)]

  摘要：

  The reaction of [Os-3(CO)(10)(MeCN)(2)] with 2-methyl-2-thiazoline at ambient temperature results in the C-H activation of the methyl substituent of the heterocyclic ligand and this gives the new compound [(mu-H)Os-3(CO)(10)(mu-eta(2)-CH2C=NCH2CH2S] (8) in 55% yield. Compound 8 undergoes decarbonylation and a further C-H bond activation by thermolysis at 98 degrees C or by treatment with trimethylamine-N-oxide to give the dihydrido cluster [(mu-H)(2)Os-3(CO)(9)(mu-eta(2)-CHC=NCH2CH2S] (9) in 45% yield. Both complexes have been characterized by elemental analyses, IR and H-1 NMR spectroscopy, together with X-ray crystallography for 8. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00354-5