[(t-Bu)C(N(2,6-(i-Pr)2C6H3))2GeCl] | 915151-35-8

• 英文名称: [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2GeCl]
• 英文别名: [Ge(((C6H3Pri2-2,6)N)2CBut)Cl]；[Ge(Piso)Cl]
• CAS: 915151-35-8
• 化学式: C₂₉H₄₃ClGeN₂
• 分子量: 527.717
• InChiKey: GZIHRSIVBHEZSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2GeCl] 在 KC₈ 作用下， 以 四氢呋喃 为溶剂， 生成 [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2S*2THF
  参考文献：
  名称：

  Synthesis and Characterization of an Amidinate-Stabilized Bisgermylene Oxide and Sulfide

  摘要：

  The synthesis and characterization of the amidinate-stabilized bisgermylene oxide and sulfide [(LGe)-Ge-2-E-GeL2] (E = 0 (2), S (3); L-2 = (BuC)-C-t(NAr)(2), Ar = 2,6-(Pr2C6H3)-C-i) are described. Compound 2 was prepared by the reaction of two equivalents of [L2GeCl] (1) with Me3NO and two equivalents of KC8 in THF. It is proposed that the reaction proceeds through an [(LGe1)-Ge-2] intermediate, which then reacts with Me3NO to form 2. Similarly, the reaction of two equivalents of 1 with elemental sulfur and two equivalents of KC8 in THE afforded 3. Compounds 2 and 3 have been characterized by NMR spectroscopy and X-ray crystallography.

  DOI：

  10.1021/om101194f

文献信息

• Synthesis, characterisation and reactivity of germanium(ii) amidinate and guanidinate complexes
  作者：Cameron Jones、Richard P. Rose、Andreas Stasch

  DOI：10.1039/b801168k

  日期：——

  Reactions of lithium salts of the bulky guanidinate ligands, [ArNC(NR2)NAr](-) (NR2 = N(C6H11)2 (Giso-) and cis-NC5H8Me2-2,6 (Pipiso-); Ar = C6H3Pri2-2,6), with GeCl2.dioxane afforded the heteroleptic germylenes, [(Giso)GeCl] and [(Pipiso)GeCl], the former of which was structurally characterised. The further reactivity of these and the related complexes, [(Piso)GeCl] and [(Priso)GeCl] (Piso- = [ArNC(Bu(t))NAr]-

  庞大的胍盐配体锂盐[ArNC（NR2）NAr]（-）（NR2 = N（C6H11）2（Giso-）和cis-NC5H8Me2-2,6（Pipiso-）; Ar = C6H3Pri2-2 ，6），用GeCl 2-二恶烷提供杂配的亚二甲苯基，[（Giso）GeCl]和[（Pipiso）GeCl]，其前者具有结构特征。这些和相关配合物[（Piso）GeCl]和[（Priso）GeCl]（Piso- = [ArNC（Bu（t））NAr]-，Priso- = [ArNC（NPri2）NAr]- ）已被调查。盐消除反应产生了新的单体络合物[[（Piso）Ge（NPri2）]和[（Piso）GeFeCp（CO）2]，而配体置换反应提供了杂金属物质[[Piso）Ge（Cl） W（CO）5）]。用GaCl3从[（Priso）GeCl]中提取氯离子，得到了结构特征性的接触离子对[[Priso）Ge] [GaCl4]。此外，
• Synthetic, structural and theoretical studies of amidinate and guanidinate stabilised germanium(i) dimers
  作者：Shaun P. Green、Cameron Jones、Peter C. Junk、Kai-Alexander Lippert、Andreas Stasch

  DOI：10.1039/b610645e

  日期：——

  The neutral germanium(i) dimers, [Ge(Piso)}(2)] and [Ge(Giso)}(2)], Piso = [(ArN)(2)CBu(t)](-), Giso = [(ArN)(2)CNPr(i)(2)](-), Ar = C(6)H(3)Pr(i)(2)-2,6, which are stabilised by bulky amidinate and guanidinate ligands respectively, have been prepared by reduction of the corresponding germanium(ii) chlorides, [Ge(Piso)Cl] and [Ge(Giso)Cl]; theoretical studies suggest that the Ge-Ge bonds of [Ge(Piso)}(2)]

  中性锗（i）二聚体[Ge（Piso）}（2）]和[Ge（Giso）}（2）]，Piso = [（ArN）（2）CBu（t）]（-）， Giso = [（ArN）（2）CNPr（i）（2）]（-），Ar = C（6）H（3）Pr（i）（2）-2,6，它们通过庞大的a胺和通过还原相应的氯化锗（ii），[Ge（Piso）Cl]和[Ge（Giso）Cl]分别制备了胍盐配体。理论研究表明，[Ge（Piso）}（2）]和[Ge（Giso）}（2）]的Ge-Ge键与它们的HOMO相关，而它们的LUMO具有大量的Ge-Ge pi键特点。