| 302917-63-1

• CAS: 302917-63-1
• 化学式: C₇H₇O₃S*C₃₇H₃₁OP₂Pd
• 分子量: 831.217
• InChiKey: GBDWFPGCKWKTCR-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  生成 钯
  参考文献：
  名称：

  On the mechanism of hydroesterification of styrene using an in situ-formed cationic palladium complex

  摘要：

  The mechanism of hydroesterification of styrene using in situ-formed Pd(OTs)(2)(PPh3)(2) from Pd(OAc)(2), PPh3 and TsOH in methanol has been investigated by isolation and characterisation of catalytically active intermediates. From reaction mixtures, Pd-hydridocarbonyl and Pd-acyl complexes were isolated and characterised, based on which a Pd hydride mechanism has been proposed. Formation of palladium hydride species has also been confirmed by P-31-NMR experiments. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00041-3
• 作为产物：
  描述：

  四(三苯基膦)钯 、 一氧化碳 、 对甲苯磺酸一水合物 以 not given 为溶剂， 生成
  参考文献：
  名称：

  On the mechanism of hydroesterification of styrene using an in situ-formed cationic palladium complex

  摘要：

  The mechanism of hydroesterification of styrene using in situ-formed Pd(OTs)(2)(PPh3)(2) from Pd(OAc)(2), PPh3 and TsOH in methanol has been investigated by isolation and characterisation of catalytically active intermediates. From reaction mixtures, Pd-hydridocarbonyl and Pd-acyl complexes were isolated and characterised, based on which a Pd hydride mechanism has been proposed. Formation of palladium hydride species has also been confirmed by P-31-NMR experiments. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00041-3