[((R)-BINAP)(PMe3)PtH][BF4] | 937792-39-7

• 英文名称: [((R)-BINAP)(PMe3)PtH][BF4]
• CAS: 937792-39-7
• 化学式: BF₄*C₄₇H₄₂P₃Pt
• 分子量: 981.656
• InChiKey: WNEKSVFPRQIEGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氘代氯仿 、 [((R)-BINAP)(PMe3)PtH][BF4] 以 氘代氯仿 、 正戊烷 为溶剂， 生成 [((rac)-BINAP)(PMe3)PtCl][BF4]
  参考文献：
  名称：

  Room-Temperature β-H Elimination in (P₂P)Pt(OR) Cations:  Convenient Synthesis of a Platinum Hydride

  摘要：

  In situ-generated [(BINAP)(PMe3)Pt][BF4](2) reacts with benzyl alcohol at RT to yield [(BINAP)(PMe3)Pt-H][BF4] and benzaldehyde. This reactivity contrasts similarly ligated platinum-alkyl species, which are stable to beta-hydride elimination even at elevated temperatures. Protonolysis of the platinum hydride leads to a species that is readily substituted by weakly coordinating ligands (acetone, pentafluorobenzonitrile).

  DOI：

  10.1021/om061105z
• 作为产物：
  描述：

  苯甲醇 、 [((R)-BINAP)(PMe3)PtI][I] 、 silver tetrafluoroborate 以 硝基甲烷 为溶剂， 以64%的产率得到[((R)-BINAP)(PMe3)PtH][BF4]
  参考文献：
  名称：

  Room-Temperature β-H Elimination in (P₂P)Pt(OR) Cations:  Convenient Synthesis of a Platinum Hydride

  摘要：

  In situ-generated [(BINAP)(PMe3)Pt][BF4](2) reacts with benzyl alcohol at RT to yield [(BINAP)(PMe3)Pt-H][BF4] and benzaldehyde. This reactivity contrasts similarly ligated platinum-alkyl species, which are stable to beta-hydride elimination even at elevated temperatures. Protonolysis of the platinum hydride leads to a species that is readily substituted by weakly coordinating ligands (acetone, pentafluorobenzonitrile).

  DOI：

  10.1021/om061105z