| 168842-73-7

• CAS: 168842-73-7
• 化学式: C₃₀H₂₁ClMoO₃
• 分子量: 560.888
• InChiKey: KUZPTBLILBIIEY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  MoH(C₅H₄C₁₀H₇(C₆H₅)2)(CO)3 在 CHCl₃ 作用下， 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Chemistry of molybdenum complexes with (triphenylmethyl)allene

  摘要：

  The cationic allene complex [Mo(eta(5)-C5H5)(CO)(3)(eta(2)-CH2=C=CHCPh(3))]BF4 1, was converted into the dihydronaphthyl complex [Mo(eta(5)-C5H5)(CO)(3)(C(10)H(7)Ph(2))] in the presence of KSCN as the major product. When the reaction was carried out at high concentration, the allylic complex [Mo(eta(5)-C5H5) (CO)(2){eta(3)-CH2C(COC(10)H(7)Ph(2))CHCPh(3)}] was isolated as a minor product. Reaction of allene with the dihydronaphthyl complex also induced insertion of CO followed by C-C coupling to give the allylic complex [Mo(eta(5)-C5H5)(CO)(2){eta(3)-CH2C(COC(10)H(7)Ph(2))CH2}]. In CH CI, migration of the organic moiety on Mo in the dihydronaphthyl to the C5H5 ligand occurred giving [MoCl{eta(5)-C5H4(C(10)H(7)Ph(2))}(CO)(3)]. In tetrahydrofuran and MeCN, similar reactions gave [MoH{eta(5)-C5H4(C(10)H(7)Ph(2))}(CO)(3)] and C5H5(C(10)H(7)Ph(2)) respectively. Under thermolytic conditions [Mo(eta(5)-C5H5)(CO)(2)(PPh(3))(C(O)C(10)H(7)Ph(2))] was also converted into [MoCl{eta(5)-C5H4(C(10)H(7)Ph(2))}(CO)(2)(PPh(3))]. The latter complex and [W(eta(5)-C5H5)(CO)(3)(C(10)H(7)Ph(2))] have been characterized by X-ray diffraction analysis.

  DOI：

  10.1039/dt9950002351