| 175854-08-7

• CAS: 175854-08-7
• 化学式: C₂₀H₂₅O₃P₂Ru*F₆P
• 分子量: 621.398
• InChiKey: NGQJEVLPDRVSLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 乙氧基乙炔 以 氘代丙酮 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, nucleophilic attack on, and rearrangement of cationic ruthenafurans: X-ray crystal structures of [Ru(CO)₂{C(Ph)NHCMe₃}(CH₂CO₂Et)(PMe₂Ph)₂][PF₆] and [Ru(CO)₂{C(Me)CHC(O)OEt}(PMe₂Ph)₂][PF₆]

  摘要：

  The methyl-substituted ruthenafuran 5 rearranges at room temperature by dismantling and reassembly of the five-membered ring, yielding 7 and then 8: the conversion is catalysed by Me(3)CNH(2); in contrast Me(3)CNH(3) attacks 2, the phenyl analogue of 5, to give a stable non-cyclic aminocarbene complex 3.

  DOI：

  10.1039/cc9960000261
• 作为产物：
  描述：

  六氟磷酸银 、 、 一氧化碳 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, nucleophilic attack on, and rearrangement of cationic ruthenafurans: X-ray crystal structures of [Ru(CO)₂{C(Ph)NHCMe₃}(CH₂CO₂Et)(PMe₂Ph)₂][PF₆] and [Ru(CO)₂{C(Me)CHC(O)OEt}(PMe₂Ph)₂][PF₆]

  摘要：

  The methyl-substituted ruthenafuran 5 rearranges at room temperature by dismantling and reassembly of the five-membered ring, yielding 7 and then 8: the conversion is catalysed by Me(3)CNH(2); in contrast Me(3)CNH(3) attacks 2, the phenyl analogue of 5, to give a stable non-cyclic aminocarbene complex 3.

  DOI：

  10.1039/cc9960000261