Steric effects of phosphorus ligands: cis/trans distributions of W(CO)4L2 products
作者:Lois M. Ounapu、John A. Mosbo、John M. Risley、Bruce N. Storhoff
DOI:10.1016/s0022-328x(00)96190-4
日期:1980.8
The cis/trans productdistribution in the reaction of phosphines with W(CO)4(Me2N(CH2)3NMe2 depends on ligand size; the smaller the ligand the greater the cis/trans ratio. The ratios range from 2.9 to 0 for PPh2Me and P(o-Tol)3, respectively.