beryllium bis(3-chlorothiopentane-2,4-dionate) | 94881-35-3

• 英文名称: beryllium bis(3-chlorothiopentane-2,4-dionate)
• 英文别名: Be(acacSCl)2
• CAS: 94881-35-3
• 化学式: C₁₀H₁₂BeCl₂O₄S₂
• 分子量: 340.253
• InChiKey: WXZKJTUCGNYHAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三乙基乙烯基硅烷 、 beryllium bis(3-chlorothiopentane-2,4-dionate) 以 not given 为溶剂， 生成 beryllium bis(3-[β-(triethylsilyl)-β-chloroethylthio]-2,4-pentanedionate)
  参考文献：
  名称：

  Synthesis and study of beryllium bis{3-[β-(triethylsilyl)-β-chloroethylthio]-2,4-pentanedionate}

  摘要：

  A silicon-containing metal chelate is prepared by the addition of beryllium bis(3-chlorothiopentane-2,4-dionate) to vinyltriethylsilane. The compound was isolated by chromatography, and its composition was determined by elemental analysis. The compound was identified as beryllium bis{3-[beta-(triethylsilyl)-beta-chloroethylthio]-2,4-pentanedionate}. To confirm this structure, the compound was converted into the pyrazole derivative by the reaction with hydrazine, and the product was examined by mass spectrometry.

  DOI：

  10.1134/s1070363206080160
• 作为产物：
  描述：

  bis(acetylacetonato)beryllium(II) 、 二氯化硫 以 not given 为溶剂， 生成 beryllium bis(3-chlorothiopentane-2,4-dionate)
  参考文献：
  名称：

  Synthesis and study of beryllium bis{3-[β-(triethylsilyl)-β-chloroethylthio]-2,4-pentanedionate}

  摘要：

  A silicon-containing metal chelate is prepared by the addition of beryllium bis(3-chlorothiopentane-2,4-dionate) to vinyltriethylsilane. The compound was isolated by chromatography, and its composition was determined by elemental analysis. The compound was identified as beryllium bis{3-[beta-(triethylsilyl)-beta-chloroethylthio]-2,4-pentanedionate}. To confirm this structure, the compound was converted into the pyrazole derivative by the reaction with hydrazine, and the product was examined by mass spectrometry.

  DOI：

  10.1134/s1070363206080160

文献信息

• Synthesis and investigation of organosilicon dendrimers based on octavinylsilsesquioxane and sulfenyl chlorides of metal acetylacetonates
  作者：M. V. Tutov、N. P. Shapkin、E. I. Karpova、V. V. Bazhenov、A. B. Slobodyuk

  DOI：10.1134/s107036321204007x

  日期：2012.4

  The addition of sulfenyl chlorides of metal acetylacetonates to octavinylsilsesquioxane was studied. The addition was shown to proceed at four of the eight vinyl groups of the octavinylsilsesquioxane, without the formation of cross-linked polymers. This allowed us to synthesize with high yields new non-functianalized and functianalized dendrimers based on octavinylsilsesquioxane and the sulfenyl chlorides of metal acetylacetonates.