2,2'-bis(acetyl-ferrocenyl)propane | 917500-99-3

• 英文名称: 2,2'-bis(acetyl-ferrocenyl)propane
• CAS: 917500-99-3
• 化学式: C₂₇H₂₈Fe₂O₂
• 分子量: 496.212
• InChiKey: BKQLWIXRPLKJHY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,2'-bis(acetyl-ferrocenyl)propane 、 三氯氧磷 在 sodium acetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2,2'-bis(CH2CCl-ferrocenyl)propane
  参考文献：
  名称：

  Studies on the synthesis of novel 2,2′-bis(ferrocenyl)propane derivatives and their reactivity with metal carbonyl clusters

  摘要：

  The reaction of new ferrocenylacetylene HC=C(C5H5FeC5H3)C(CH3)(2)Fc'C=CH (1; Fc'=C5H4FeC5H4) with Co-2(CO)(8) has been studied and the spectra and molecular structure of complexes [HC=C(C5H5FeC5H3)C(CH3)2Fc'C=CH][Co-2(CO)(6)](n) [n = 1, (4); n = 2, (5)] have been determined. Novel complex [FcC(CH3)(2)FcCH=C]FeCo2(CO)(9) (6; Fc = C5H5FeC5H4) has been synthesized by using a nuclear expanding reaction of complex [FcC(CH3)(2)Fc'=CH]Co-2(CO)(6) (3) with Fe-2(CO)(9) and the structural characterization of complex 6 was accomplished by elemental analysis, IR, H-1, C-13 NMR and MS. The electrochemical properties of the compounds with ferrocenylacetylene reveal that there is significant electronic communication between the ferrocenyl groups. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.05.022