| 163231-16-1

• CAS: 163231-16-1
• 化学式: C₁₃H₂₂N*Cl₄ORe
• 分子量: 536.343
• InChiKey: XTFIIIDFCLJACY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  末端脱氧核苷酸转移酶 、 以 甲醇 、 氯仿 为溶剂， 以68%的产率得到chloro(3-thiapentane-1,5-dithiolato)oxorhenium(V)
  参考文献：
  名称：

  Synthesis and molecular structure of chloro(3-thiapentane-1,5-dithiolato)oxorhenium(V)

  摘要：

  Reaction of [BzEt(3)N][ReOCl4] (1) with 0.9 equiv, of 3-thiapentane 1,5-dithiol (HSSSH) in chloroform delivers [ReO(SSS)Cl] (2). The chloro ligand can be substituted by mercaptides when 2 is heated with an excess of a mercaptane, e.g. C2H5SH, in acetonitrile. Single crystal X-ray analysis of 2 shows square-pyramidal geometry.

  DOI：

  10.1016/0020-1693(94)04351-u
• 作为产物：
  描述：

  ammonium perrhenate 、 苄基三乙基氯化铵 在 HCl 、 ethanol 作用下， 以 乙醇 为溶剂， 以82.5%的产率得到
  参考文献：
  名称：

  Neutral oxorhenium(V) complexes with tridentate dithiolates and monodentate alkane- or arene-thiolate coligands

  摘要：

  Oxorhenium(v) complexes [ReO(SXS)(SR)] (where HSXSH = 3-thia- or 3-oxa-pentane-1,5-dithiol and RSH = alkane- or arene-thiol) have been synthesized by a ligand exchange reaction of [NEt(3)(CH(2)Ph)][ReOCl4] with a mixture of HSXSH and RSH in methanol-acetonitrile. The compounds were purified by column chromatography or preparative TLC and characterized by elemental analysis, infrared and H-1 NMR spectroscopy. The structure of (4-methoxybenzenethiolato)(3-oxapentane-1,5-dithiolato)oxorhenium(v) has been determined by X-ray crystallography. The co-ordination is square-pyramidal with the Re atom displaced from the basal plane by 0.728 Angstrom. Co-ordination of the ether group is indicated by the short Re-O(ether) bond distance of 2.103 Angstrom.

  DOI：

  10.1039/dt9950002277

文献信息

• Unexpected formation of the new oxorhenium (V) complex [ReO(NH(CH2CH2S)2)(SC6H5)] obtained by NC cleavage of the tripodal ligand N(CH2CH2SH)3
  作者：M. Glaser、H. Spies、R. Berger、F.E. Hahn、T. Lügger、B. Johannsen

  DOI：10.1016/s0020-1693(96)05461-8

  日期：1997.4

  The tripodal ligand 2,2',2''-nitrilotris(ethanethiol) (N(SH)(3)=N(CH2CH2SH)(3)) reacts with [ReO(SC6H5)(4)](-) as rhenium(V) precursor to give unexpectedly the square-pyramidal oxorhenium(V) species [ReO(NH(CH2CH2S)(2))(SC6H5)] (1). The reaction mechanism is assumed to involve cleavage of the chelate ligand catalysed by the metal core. Treatment of 1 with methyl iodide at room temperature leads to substitution of the thiolate ligand by iodide and methylation of the amine nitrogen to the compound [ReO(NCH3(CH2CH2S)(2))I] (2).