1-formylferrocene 4-methoxybenzoylhydrazone | 128138-47-6

• 英文名称: 1-formylferrocene 4-methoxybenzoylhydrazone
• CAS: 128138-47-6
• 化学式: C₁₉H₁₈FeN₂O₂
• 分子量: 362.211
• InChiKey: CZWRCEFGAQMUBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯二茂钛 、 1-formylferrocene 4-methoxybenzoylhydrazone 以 氯仿 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Transition and Non-Transition Metal Complexes with 1-Formylferrocene 4-Methoxybenzoylhydrazone and 1-Acetylferrocene 4-Methoxybenzoylhydrazone

  摘要：

  DOI：

  10.1080/00945719909349461
• 作为产物：
  描述：

  二茂铁甲醛 、 乙酰基二茂铁 以 甲醇 为溶剂， 以80%的产率得到1-formylferrocene 4-methoxybenzoylhydrazone
  参考文献：
  名称：

  Transition and Non-Transition Metal Complexes with 1-Formylferrocene 4-Methoxybenzoylhydrazone and 1-Acetylferrocene 4-Methoxybenzoylhydrazone

  摘要：

  DOI：

  10.1080/00945719909349461

文献信息

• Preparation, characterization, electrochemical studies and crystal structure determination of salicylaldehyde–aroylhydrazone, ferrocenyl–aroylhydrazone and salicylaldehyde–ferrocenoylhydrazone complexes of indium
  作者：Yaofeng Yuan、Zhong Cao、Nanyan Fu、Jitao Wang、Linhong Weng、Antonio Bezerra de Carvalho、Clovis Peppe

  DOI：10.1016/s0022-328x(01)00961-5

  日期：2001.12

  The reaction of triethylindium with salicylaldehyde-aroylhydrazone, C6H4(o-OH)-CHNNH-C(O)C6H4-X (X =p-H, p-OCH3, p-NO2, m-NO2, o-OH), yields the tetrahydrofuran (THF) adduct of (C14H9N2O2X)(2)InC2H5. With formylferrocenyl-aroylhydrazones C5H5FeC5H4-CHNNH-C(O)C6H4-X (X=p-H, p-OCH3, p-NO2, m-NO2, P-Cl, o-Cl), the diethylindium-hydrazone complex, (C18H14N2OFeX)In(C2H5)(2), was formed. With salicylaldehyde-ferrocenoylhydrazone, C6H4(o-OH)-CHNNH-C(O)C5H4FeC5H5, the monohydrazone complex (C18H15N2O2Fe)In(C2H5)(2) tetrahydrofuran solvate was obtained. The crystal structures of the p-OCH3 derivatives of the first two series of complexes and of the ferrocenoylhydrazone derivative were determined. In the solid state, the three complexes are dimers, containing a set of seven, three and five fused rings, respectively. In every case, it was observed a symmetric anti arrangement of fused rings in relation to a central In2O2 four-membered ring, resulting in a configuration that resembles a chair. Cyclic voltammetric studies on the ferrocenylaroylhydrazone complexes revealed electron transference from the ferrocene group towards the indium atom, while for the salicilaldehyde-ferrocenoyl complex this was not observed. (C) 2001 Elsevier Science B.V. All rights reserved.