cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex) | 183293-92-7

• 英文名称: cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)
• 英文别名: trans-dichloro[S-methyl p-tolyl sulfoxide](pyridine)platinum(II)；cis-dichloropyridine(methyl-para-tolylsulfoxide)platinum(II)；cis-[Pt(MeSO-p-Tol)(pyridine)Cl2]；(-)-cis-[Pt(p-MeC6H4SOCH3)(C5H5N)Cl2]
• CAS: 183293-92-7；183506-91-4；1209494-94-9
• 化学式: C₁₃H₁₅Cl₂NOPtS
• 分子量: 499.32
• InChiKey: PPJCXGYWKFYNJB-USOZLSCGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex) 以 二氯甲烷 为溶剂， 生成 trans-dichloropyridine(methyl-para-tolylsulfoxide)platinum(II)
  参考文献：
  名称：

  摘要：

  Photochemical behavior of platinum(H) sulfoxide-containing complexes in methyl chloride was studied by polarimetry and H-1 NMR spectroscopy.

  DOI：

  10.1023/a:1013096802361
• 作为产物：
  描述：

  trans-dichloropyridine(methyl-para-tolylsulfoxide)platinum(II) 以 甲苯 为溶剂， 以15%的产率得到cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)
  参考文献：
  名称：

  摘要：

  Photochemical behavior of platinum(H) sulfoxide-containing complexes in methyl chloride was studied by polarimetry and H-1 NMR spectroscopy.

  DOI：

  10.1023/a:1013096802361

文献信息

• Reznikov; Krivchun; Bel'skii, Russian Journal of General Chemistry, 2000, vol. 70, # 7, p. 1032 - 1036
  作者：Reznikov、Krivchun、Bel'skii、Skvortsov

  DOI：——

  日期：——
• ——
  作者：D. A. de Vekki、V. N. Spevak、N. K. Skvortsov

  DOI：10.1023/a:1011357929566

  日期：——

  The reactions of the optically active geometric isomers of the platinum(II) complex (-)-[Pt(Me-p-TolSO)(Py)Cl-2] with several nucleophilic reagents (Py, Ph3PS, Ph3P, Ph3As, and Me2SO) were studied by optical rotatory dispersion, IR spectroscopy, and H-1 and P-31 NMR spectroscopy. A mechanism for the reaction is proposed.