(TPP)In radical | 102513-31-5

• 英文名称: (TPP)In radical
• CAS: 102513-31-5
• 化学式: C₄₄H₂₈InN₄
• 分子量: 727.553
• InChiKey: YYJZLOGQDDAARW-GGIBPTKLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (TPP)In(C2H5) 以 2-甲基四氢呋喃 为溶剂， 生成 (TPP)In radical
  参考文献：
  名称：

  乙基铟（III）四苯基卟啉中碳-铟键的光化学解离。在2-甲基四氢呋喃中形​​成两性离子卟啉的证据

  摘要：

  Ethylindium（III）四苯基卟啉，C 2 ħ 5 -In（III）TPP，经过光敏反应作为C均裂2 ħ 5 -In键以产生两性离子铟（III）四苯基卟啉，在（III）+ TPP - ，其中正电荷位于中心铟原子上，负电荷位于四苯基卟啉（TPP）配体上。

  DOI：

  10.1016/0009-2614(86)85174-0

文献信息

• Kadish; Maiya; Xu, Inorganic Chemistry, 1989, vol. 28, # 13, p. 2518 - 2523
  作者：Kadish、Maiya、Xu

  DOI：——

  日期：——
• Electron-Transfer Reactions between C60 and Radical Ions of Metalloporphyrins and Arenes
  作者：Dirk M. Guldi、Pedatsur Neta、Klaus-Dieter Asmus

  DOI：10.1021/j100068a022

  日期：1994.4

  Electron-transfer reactions with C-60 leading to the singly reduced and oxidized radical ions, C-60(.-) and C-60(.+) have been studied by pulse radiolysis. pi-Radical anions of several metalloporphyrins (tetraphenyl- and tetrapyridylporphyrins) reduced C-60 With rate constants of (1-3) x 10(9) L mol(-1) s(-1), whereas metalloporphyrins which are reduced at the metal center (Ni-I, Cu-I, Cr-II) reacted with C-60 somewhat more slowly, with rate constants of (0.7-2.3) x 10(8) L mol(-1) s(-1). Sb(V)OEP(.-) (octaethylporphyrin) did not reduce C-60 (k less than or equal to 10(7) L mol(-1) s(-1)) and Sn-IV(Ph)(3)(Py)P-.- reacted in an equilibrium process (K = 14). Electron transfer from C-60 to several aromatic radical cations (derived from naphthalene, biphenyl, m-terphenyl, and trans-stilbene) also took place rapidly (k = (2.5-7.9) x 10(9) L mol(-1) s(-1)) to produce C-60(.+); the radical cations of anthracene and chrysene, on the other hand, did not exhibit any significant reactivity toward C-60.