| 148484-94-0

• CAS: 148484-94-0
• 化学式: C₁₄H₁₇ClN₂Pd
• 分子量: 355.175
• InChiKey: MBMNGSQLIFLFPS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 solid 为溶剂， 生成 di-μ-chlorobis{(2-phenylpyridine)palladium(II)} 、 异丙胺
  参考文献：
  名称：

  摘要：

  The complex [Pd(2-Phpy)(mu -Cl)](2) reacts with pyridines (L=pyridine, alpha -picoline and gamma -picoline), amines (L=isopropylamine, tert-butylamine) and ammonia to form the corresponding ortho-palladated derivatives [Pd(2-Phpy)ClL]. The compounds have been characterized by C, H and N analyses and spectroscopic methods (IR and H-1 and C-13 NMR). TG, DTG and DSC studies of the complexes were carried out in dynamic nitrogen atmosphere, From DSC analyses the heats of decomposition were calculated. The kinetics of the first step of thermal decomposition were evaluated from TG data by isothermal methods for L=pyridine and isopropylamine. The activation energies obtained are in the range 90-100 kJ mol(-1). The best fitting for data was observed for R2 and A1.5 kinetic models.

  DOI：

  10.1023/a:1013118929427
• 作为产物：
  描述：

  di-μ-chlorobis{(2-phenylpyridine)palladium(II)} 、 异丙胺 以 丙酮 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  摘要：

  The complex [Pd(2-Phpy)(mu -Cl)](2) reacts with pyridines (L=pyridine, alpha -picoline and gamma -picoline), amines (L=isopropylamine, tert-butylamine) and ammonia to form the corresponding ortho-palladated derivatives [Pd(2-Phpy)ClL]. The compounds have been characterized by C, H and N analyses and spectroscopic methods (IR and H-1 and C-13 NMR). TG, DTG and DSC studies of the complexes were carried out in dynamic nitrogen atmosphere, From DSC analyses the heats of decomposition were calculated. The kinetics of the first step of thermal decomposition were evaluated from TG data by isothermal methods for L=pyridine and isopropylamine. The activation energies obtained are in the range 90-100 kJ mol(-1). The best fitting for data was observed for R2 and A1.5 kinetic models.

  DOI：

  10.1023/a:1013118929427