Adams, Richard D.; Chen, Gong; Lii, Jau-Ching, Inorganic Chemistry, 1991, vol. 30, # 5, p. 1007 - 1013
作者:Adams, Richard D.、Chen, Gong、Lii, Jau-Ching、Wu, Wengan
DOI:——
日期:——
Adams, Richard D.; Wu, Wengan, Inorganic Chemistry, 1991, vol. 30, # 19, p. 3605 - 3612
作者:Adams, Richard D.、Wu, Wengan
DOI:——
日期:——
Adams, Richard D.; Lii, Jau-Ching; Wu, Wengan, Inorganic Chemistry, 1991, vol. 30, # 19, p. 3613 - 3617
作者:Adams, Richard D.、Lii, Jau-Ching、Wu, Wengan
DOI:——
日期:——
Adams, Richard D.; Pompeo, Michael P.; Wu, Wengan, Inorganic Chemistry, 1991, vol. 30, # 10, p. 2425 - 2432
作者:Adams, Richard D.、Pompeo, Michael P.、Wu, Wengan
DOI:——
日期:——
Unsaturation in a high-nuclearity metal carbonyl cluster complex. Synthesis, structures, and interconversions of Pt2Os4(CO)12(COD)2 and Pt2Os4(CO)11(COD)2
作者:Richard D. Adams、Wengan Wu
DOI:10.1021/om00047a019
日期:1991.1
The two new platinum-osmium carbonyl cluster complexes Pt2Os4(CO)12(COD)2 (1) and Pt2Os4(CO)11(COD)2 (2) were obtained from the reaction of Pt2Os4(CO)18 with 1,5-cyclooctadiene (COD) at 97-degrees-C. Both compounds consist of a bicapped Os4 tetrahedron. Compound 1 is coordinatively saturated, while compound 2 is coordinatively unsaturated. The latter contains several unusually short metal-metal bonds and readily adds CO to give 1 in good yield.