(μ-dimethylselenide)bis[dicarbonyl(η5-cyclopentadienyl)manganese(I)] | 110296-77-0

• 英文名称: (μ-dimethylselenide)bis[dicarbonyl(η5-cyclopentadienyl)manganese(I)]
• 英文别名: [(η5-cyclopentadienyl)Mn(CO)2]2SeMe2；[CpMn(CO)2]2SeMe2
• CAS: 110296-77-0
• 化学式: C₁₆H₁₆Mn₂O₄Se
• 分子量: 461.137
• InChiKey: BDIAQAMLDNFKQB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (μ-dimethylselenide)bis[dicarbonyl(η5-cyclopentadienyl)manganese(I)] 以 neat (no solvent, solid phase) 为溶剂， 生成 锰 、 manganese(II) selenide
  参考文献：
  名称：

  Syntheses, molecular structures, and thermal decomposition of cyclopentadienyldicarbonylmanganese chalcogenide derivatives

  摘要：

  Transmetallation of the dichalcogenide complexes [CpMn(CO)(2)](2)(mu-X-2) (X = S or Se) with M(CO)(5)(thf) (M = Cr or W) afforded new heterometallic complexes CpMn(CO)(2)(ASe(2))Cr(CO)(5), CpMn(CO)(2)(mu-Se-2)[Cr(CO)(5)](2), CpMn(CO)(2)(mu-X-2)[W(CO)(5)](2) (X = S or Se), and CpMn(CO)(2)(mu-Se-2)[Cr(CO)(5)][W(CO)(5)]. According to the X-ray diffraction data, their molecular structures contain the cyclic MnX2 fragments coordinated by one or two M(CO)(5) groups via the X atoms. Study of thermal decomposition of the manganese complexes with different Mn : M : X ratios (M = Cr, W; X = S, Se, Te) by differential scanning calorimetry (DSC) and thermogravimetry demonstrated that this process took place at rather low temperatures (100-400degreesC) and was accompanied by complete elimination of the CO groups followed by elimination of the Cp groups. At any metal to chalcogen ratio, the resulting inorganic chalcogenides contained no impurities of metal oxides and carbides.

  DOI：

  10.1023/b:rucb.0000019888.02470.3e
• 作为产物：
  描述：

  三羰基(η-环戊二烯基)合锰 、 二甲基硒 在 THF 作用下， 以 四氢呋喃 为溶剂， 以46%的产率得到(μ-dimethylselenide)bis[dicarbonyl(η5-cyclopentadienyl)manganese(I)]
  参考文献：
  名称：

  Bremer, Gerhard; Boese, Roland; Keddo, Mustafa, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1986, vol. 41, # 8, p. 981 - 986

  摘要：

  DOI：

文献信息

• Pasynskii; Grigor'ev; Torubaev, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 12, p. 1833 - 1841
  作者：Pasynskii、Grigor'ev、Torubaev、Lysenko、Dobrokhotova、Minin、Grinberg

  DOI：——

  日期：——