| 68949-09-7

• CAS: 68949-09-7
• 化学式: Al₂ClH₆LiO₆
• 分子量: 198.401
• InChiKey: QVASHMCSZHOIEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -6.07
• 重原子数：
  10.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  189.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  对苯二甲酸二甲酯 、 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 生成 [LiAl2(OH)6]2[terephthalate]
  参考文献：
  名称：

  Alkaline hydrolysis of dimethyl terephthalate in the presence of [LiAl2(OH)6]Cl·2H2O

  摘要：

  The alkaline hydrolysis of dimethyl terephthalate (DMT) in the presence of [LiAl2(OH)(6)]Cl has been investigated to demonstrate a possible application of anion exchange facility of layered double hydroxides (LDHs) to control chemical reactions. The results show that (i) in the alkaline hydrolysis of DMT in the presence of [LiAl2(OH)(6)]Cl, most of the interlayer Cl- of [LiAl2(OH)(6)]Cl is quickly replaced by OH- in the alkaline solution because the LDH host favors OH- more; (ii) the alkaline hydrolysis of DMT in the presence of [LiAl2(OH)(6)]Cl is faster than the reaction of DMT and [LiAl2(OH)(6)]OH; (iii) The hydrolysis of DMT in a buffer solution of pHz approximate to 8 takes longer time to reach equilibrium than the alkaline hydrolysis of DMT in the presence of [LiAl2(OH)(6)]Cl. It is believed that the selective anion exchange chemistry of the LDH plays a key role in storage and controlled release of active reactant, that is, OH-, thus make the hydrolysis proceeds in a controlled way. (c) 2006 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2006.07.038
• 作为产物：
  描述：

  aluminum trihydroxide 、 lithium chloride 以 水 为溶剂， 生成
  参考文献：
  名称：

  Alkaline hydrolysis of dimethyl terephthalate in the presence of [LiAl2(OH)6]Cl·2H2O

  摘要：

  The alkaline hydrolysis of dimethyl terephthalate (DMT) in the presence of [LiAl2(OH)(6)]Cl has been investigated to demonstrate a possible application of anion exchange facility of layered double hydroxides (LDHs) to control chemical reactions. The results show that (i) in the alkaline hydrolysis of DMT in the presence of [LiAl2(OH)(6)]Cl, most of the interlayer Cl- of [LiAl2(OH)(6)]Cl is quickly replaced by OH- in the alkaline solution because the LDH host favors OH- more; (ii) the alkaline hydrolysis of DMT in the presence of [LiAl2(OH)(6)]Cl is faster than the reaction of DMT and [LiAl2(OH)(6)]OH; (iii) The hydrolysis of DMT in a buffer solution of pHz approximate to 8 takes longer time to reach equilibrium than the alkaline hydrolysis of DMT in the presence of [LiAl2(OH)(6)]Cl. It is believed that the selective anion exchange chemistry of the LDH plays a key role in storage and controlled release of active reactant, that is, OH-, thus make the hydrolysis proceeds in a controlled way. (c) 2006 Elsevier Inc. All rights reserved.

  DOI：

  10.1016/j.jssc.2006.07.038

文献信息

• Interlamellar chemistry of hydrotalcites
  作者：A. Schutz、P. Biloen

  DOI：10.1016/0022-4596(87)90323-9

  日期：1987.6

  Exchange of silicate anions into hydrotalcite-type materials leads to the ready formation of well-ordered two-dimensional silicate sheets. The combined evidence from diffraction, NMR, and IR allows for a global identification of the reaction product. Its structure probably consists of positively charged brucitelike layers intercalated with puckered, silicic-acid-type macroanions.

  将硅酸根阴离子交换成水滑石型材料，可以容易地形成有序的二维硅酸盐片。来自衍射，NMR和IR的综合证据可以对反应产物进行全面鉴定。它的结构可能由带正电荷的水镁石层组成，中间夹有褶皱的硅酸型大阴离子。
• Selective anion-exchange intercalation of isomeric benzoate anions into the layered double hydroxide [LiAl2(OH)6]Cl·H2O
  作者：Lixu Lei、Aamir Khan、Dermot O’Hare

  DOI：10.1016/j.jssc.2005.09.012

  日期：2005.12

  All the geometric isomers of the benzoate derivatives, XC6H4CO2- (X = F, Cl, Br, OH, OCH3, NO2, CO2CH3, NH2, N(CH3)(2)) can be intercalated into the layered double hydroxide [LiAl2(OH)(6)]Cl center dot H2O in 50% (v/v) water/ethanol Solution at 80 degrees C to give fully anion-exchanged first stage intercalation compounds [LiAl2(OH)(6)]G center dot yH(2)O (G = a substituted benzoate). The observed interlayer separations of the intercalates vary from 14.3 angstrom for [LiAl2(OH)(6)](4-nitrobenzoate) center dot 2H(2)O to 20.6 angstrom for [LiA](2)(OH)(6)](3-dimethylaminobenzoate) 3H(2)O. Competitive intercalation studies using mixtures of isomeric benzoates showed that the 4-isomers and 2-isomers are the most and the least preferred anions, respectively. Comparing the calculated dipole moments of the anions with the observed isomeric intercalation preferences suggests that dipole moment may be a good general index for the preference; however, it should be remembered that the bulkiness and electronegativity of the other substituent could be very important factors that affect the preferential intercalation. (C) 2005 Elsevier Inc. All rights reserved.
• Anion exchange in lithium aluminate hydroxides
  作者：Prabir K. Dutta、Micky Puri

  DOI：10.1021/j100338a072

  日期：1989.1
• Structure and reactivity of oxovanadate anions in layered lithium aluminate materials
  作者：Jen Twu、Prabir K. Dutta

  DOI：10.1021/j100360a028

  日期：1989.11