tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese | 62980-80-7

• 英文名称: tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese
• 英文别名: diphenylcymanthrenylphosphine；diphenylphosphinocymantrene
• CAS: 62980-80-7
• 化学式: C₂₀H₁₄MnO₃P
• 分子量: 388.241
• InChiKey: TWAICUAUVVOWJL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese 以 四氢呋喃 为溶剂， 以44%的产率得到tetracarbonyl{μ-((η5-cyclopentadienyl)diphenylphosphine-P)}dimanganese
  参考文献：
  名称：

  Rausch, Marvin D.; Spink, W. Craig, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1989, vol. 19, p. 1093 - 1102

  摘要：

  DOI：
• 作为产物：
  描述：

  三羰基(η-环戊二烯基)合锰 、 二苯基氯化膦 在 正丁基锂 作用下， 以 not given 为溶剂， 以87.4%的产率得到tricarbonyl(η5-diphenylphosphinocyclopentadienyl)manganese
  参考文献：
  名称：

  The orientation of substitution in metallation of dimethylaminomethyl-, hydroxymethyl- and diphenylphospino-cymantrenes

  摘要：

  DOI：

  10.1016/s0022-328x(00)93594-0

文献信息

• A new photochemical reaction of cymanthrene derivatives
  作者：M. N. Barsegova、N. M. Loim、N. K. Baranetskaya、V. N. Setkina

  DOI：10.1007/bf00953378

  日期：1986.11
• Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands
  作者：T. V. Magdesieva、V. V. Bashilov、D. N. Kravchuk、F. M. Dolgushin、K. P. Butin、V. I. Sokolov

  DOI：10.1023/b:rucb.0000037844.93864.3c

  日期：2004.4

  Electronic structures of exohedral palladium complexes of [60]- and [70]-fullerenes with diphenylphosphinoferrocenyl, diphenylphosphinoruthenocenyl, and diphenylphosphinocymantrenyl ligands were studied by cyclic voltammetry and semiempirical quantum-chemical calculations. Probable sites of localization of electronic changes in the molecules of these complexes under electrochemical oxidation and reduction were determined.
• ——
  作者：T. V. Magdesieva、D. N. Kravchuk、V. V. Bashilov、I. V. Kusnetsova、V. I. Sokolov、K. P. Butin

  DOI：10.1023/a:1020900131485

  日期：——

  Electrochemical synthesis and voltammetric study of new heterotrimetallic exohedral derivatives of [60](-) and [70]fullerenes containing palladium and manganese atoms were carried out. The MO involved in redox transitions were determined by the semiepirical quantum-chemical calculations and by the comparison of the potentials for the redox transitions of the heterotrimetallic complexes and their fullerene and metal-containing fragments.
• Synthesis, properties, and reactivity of chromium ?-benzenedicarbonyl complexes with diphenylphosphinocymanthrenyl and diphenylphosphinomethylcymanthrenyl ligands
  作者：M. N. Estekhina、B. I. Losilkina、N. M. Loim、N. K. Baranetskaya、V. N. Setkina

  DOI：10.1007/bf00957557

  日期：1986.10