[CdCl2(η2-N,N-di-2-pyridylketonesemicarbazone)] | 1431616-65-7

• 英文名称: [CdCl2(η2-N,N-di-2-pyridylketonesemicarbazone)]
• 英文别名: [CdCl₂(η²-N,N-di-2-pyridylketonesemicarbazone)]
• CAS: 1431616-65-7
• 化学式: C₁₂H₁₁CdCl₂N₅O
• 分子量: 424.568
• InChiKey: NDOWJAXXIRRHBD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-二吡啶基酮 以 甲醇 、 乙腈 为溶剂， 反应 3.0h， 生成 [CdCl2(η2-N,N-di-2-pyridylketonesemicarbazone)]
  参考文献：
  名称：

  Spectroscopic, and electrochemical studies of [MCl2(η2-N,N-dpksc)] (M=Zn, Cd, Hg and dpksc=di-2-pyridylketone semicarbazone)

  摘要：

  A series of group 12 metal chlorides of dpksc of the type [MCl2(eta(2)-N,N-dpksc)] (M = Zn, Cd and Hg) were synthesized from the reactions between MCl2 and dpksc in refluxing CH3CN. Spectroscopic measurements performed on protophilic solutions of [MCl2(eta(2)-N,N-dpksc)] divulged sensitivity of [MCl2(eta N-2,N-dpksc-H)](-) to changes in their surroundings. Variable temperature 1H NMR studies revealed the amine protons to be more sensitive to temperature variations compared to the amide and aromatic protons. Electronic absorption spectral measurements disclosed acid-base inter-conversion between [MCl2(eta N-2,N-dpksc-H)](-) and its conjugate base [MCl2(eta N-2,N-dpksc-H)]. In dmf, the acidity of IMCl2(eta(2)-N,N-dpksc)] increases in the following order: [ZnCl2(eta(2)-N,N-dpksc)] > [CdCl2(eta(2)-N,N-dpksc)] > [HgCl2(eta(2)-N,N-dpksc)]. The electrochemical properties of IMCl2(eta(2)-N,N-dpksc)] are dominated by a series of irreversible redox transformations pointing to electrochemical decomposition of [MCl2(eta(2)-N,N-dpksc)] upon electronic transfers. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2013.02.027