antimony(5+);bis(sulfanylidene)azanium;hexachloride | 67556-29-0

• 英文名称: antimony(5+);bis(sulfanylidene)azanium;hexachloride
• CAS: 67556-29-0
• 化学式: Cl₆Sb*NS₂
• 分子量: 412.607
• InChiKey: PLUFCQLKNPQUQT-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  -18.84
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.2
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  antimony(5+);bis(sulfanylidene)azanium;hexachloride 、 苯甲腈 以 neat (no solvent) 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  A general route to N(SCl)2 + and SNS+ salts

  摘要：

  A 1:3 mixture of (NSCl)3 and AgX (where X is a 'hard' anion) in liquid SO2 act as a convenient source of [SN]X. The reactivity of salts of this SN+ cation towards sulfur and SCl2 has been examined. Reaction of (NSCl)3 with AgX (X = AsF6, SbF6 or CF3SO3) and SCl2 in liquid SO2 gave [N(SCl)2]X in high yield (> 75%). Reduction of these salts with SnCl2 provides a convenient route to the corresponding [SNS]X salts. Replacement of SCl2 by sulfur in the (NSCl)3 + AgCF3SO3 reaction yields only ca. 30% [SNS][CF3SO3]. The other main product is [S6N4][CF3SO3]2 which crystallises in the space group P2(1)/n [Z = 2, a = 8.632(4), b = 10.614(8), c = 8.387(6) angstrom, beta = 90.79(5)-degrees, R = 0.025] and shows similar intermolecular S ... O contacts to [S6N4][ClS2O6]2 [P1BAR, Z = 1, a = 7.689(1), b = 10.726(1), c = 6.614(1) angstrom, alpha = 101.00(2), beta = 114.42(2), gamma = 90.35(2)-degrees, R = 0.031]. The relative reactivities of the different SNS+ salts with PhCN lie in the order AsF6- > SbCl6- > CF3SO3- > SbF6- > AlCl4-. The structure of [PhCNSNS][AsF]6 has been determined: space group P2(1)/a, Z = 4, a = 10.824(5), b = 8.287(2), c = 13.599(3) angstrom, beta = 106.32(4)-degrees, R = 0.055.

  DOI：

  10.1039/dt9920003097
• 作为产物：
  描述：

  bis(chlorosulfur)nitrogen hexachloroantimonate 在 tin(ll) chloride 作用下， 以 liquid sulphur dioxide 为溶剂， 以70%的产率得到antimony(5+);bis(sulfanylidene)azanium;hexachloride
  参考文献：
  名称：

  Banister, Aethur J.; Rawson, Jeremy M., Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.3, 2.1.10.4, page 233 - 234
  作者：

  DOI：——

  日期：——
• Banister, Arthur J.; Kendrick, Aidan G., Journal of the Chemical Society, Dalton Transactions, 1987, p. 1565 - 1568
  作者：Banister, Arthur J.、Kendrick, Aidan G.

  DOI：——

  日期：——
• Preparation, vibrational spectra, and crystal structure of dithionitronium hexachloroantimonate(V), (S2N)(SbCl6)
  作者：Romolo Faggiani、Ronald J. Gillespie、Colin J. L. Lock、J. David Tyrer

  DOI：10.1021/ic50189a002

  日期：1978.11.1
• Dithionitronium hexachloroantimonate: A thionitrosylating reagent
  作者：Krishna K. Pandey

  DOI：10.1016/s0020-1693(00)82208-2

  日期：1986.1