(η6-C6H6)RuCl(5-hydroxy-2-(hydroxymethyl)-4-pyrone) | 1204169-40-3

• 英文名称: (η6-C6H6)RuCl(5-hydroxy-2-(hydroxymethyl)-4-pyrone)
• CAS: 1204169-40-3
• 化学式: C₁₂H₁₁ClO₄Ru
• 分子量: 355.74
• InChiKey: CKTHHNPVQXHRGV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η6-C6H6)RuCl(5-hydroxy-2-(hydroxymethyl)-4-pyrone) 、 sodium azide 以 乙醇 为溶剂， 以81%的产率得到[(η6-C6H6)Ru(μ-N3)Cl]2
  参考文献：
  名称：

  Water soluble (η6-arene) ruthenium(II) complexes incorporating marine derived bioligand: Synthesis, spectral and structural studies

  摘要：

  A series of water soluble compounds of general formula [{(eta(6)-arene)Ru(HMP) Cl}], [eta(6)-arene = eta(6)-cymene (1), eta(6)-HMB (2), eta(6)-C6H6 (3); HMP = 5-hydroxy-2-(hydroxymethyl)-4-pyrone] have been prepared by the reaction of [{(eta(6)-arene) RuCl2}(2)] with HMP. The complexes 1 and 2 react with NaN3 to give in excellent yield tetra-azido complexes [{(eta(6)-arene) Ru(mu N-3)N-3}(2)] (arene = cymene 4, HMB = 5) but similar reaction of complex 3 with NaN3 yielded di-azdo complex [{(eta(6)-C6H6)Ru(mu N-3)Cl}(2)] (6). Reaction of [{(eta(6)-arene)Ru(mu N-3)Cl}(2)] with HMP in the presence of NaOMe resulted in the formation of azido complex [{(eta(6)-arene)Ru(HMP)N-3}]. Mono and dinuclear complexes [{(eta(6)-arene)Ru(HMP)(L-1)}](+) and [{(eta(6)-arene)Ru(HMP)}(2)(mu L-2)](2+) were also prepared by the reaction of complexes 1 and 2 with the appropriate ligand, L-1 or L-2 in the presence of AgBF4 (L-1 = PyCN, DMAP; L-2 = 4,4'-bipy, pyrazine). The complexes are characterized on the basis of spectroscopic data and molecular structures of three representative compounds have been determined by single crystal X-ray diffraction study. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.006
• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 曲酸 在 NaOMe 作用下， 以 甲醇 为溶剂， 以98%的产率得到(η6-C6H6)RuCl(5-hydroxy-2-(hydroxymethyl)-4-pyrone)
  参考文献：
  名称：

  Water soluble (η6-arene) ruthenium(II) complexes incorporating marine derived bioligand: Synthesis, spectral and structural studies

  摘要：

  A series of water soluble compounds of general formula [{(eta(6)-arene)Ru(HMP) Cl}], [eta(6)-arene = eta(6)-cymene (1), eta(6)-HMB (2), eta(6)-C6H6 (3); HMP = 5-hydroxy-2-(hydroxymethyl)-4-pyrone] have been prepared by the reaction of [{(eta(6)-arene) RuCl2}(2)] with HMP. The complexes 1 and 2 react with NaN3 to give in excellent yield tetra-azido complexes [{(eta(6)-arene) Ru(mu N-3)N-3}(2)] (arene = cymene 4, HMB = 5) but similar reaction of complex 3 with NaN3 yielded di-azdo complex [{(eta(6)-C6H6)Ru(mu N-3)Cl}(2)] (6). Reaction of [{(eta(6)-arene)Ru(mu N-3)Cl}(2)] with HMP in the presence of NaOMe resulted in the formation of azido complex [{(eta(6)-arene)Ru(HMP)N-3}]. Mono and dinuclear complexes [{(eta(6)-arene)Ru(HMP)(L-1)}](+) and [{(eta(6)-arene)Ru(HMP)}(2)(mu L-2)](2+) were also prepared by the reaction of complexes 1 and 2 with the appropriate ligand, L-1 or L-2 in the presence of AgBF4 (L-1 = PyCN, DMAP; L-2 = 4,4'-bipy, pyrazine). The complexes are characterized on the basis of spectroscopic data and molecular structures of three representative compounds have been determined by single crystal X-ray diffraction study. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.006