hydroxo(phthalocyanine-2,3:9,10:16,17:23,24-tetrakis(dicarboxanhydride))aluminium(III) | 873430-64-9

• 英文名称: hydroxo(phthalocyanine-2,3:9,10:16,17:23,24-tetrakis(dicarboxanhydride))aluminium(III)
• 英文别名: octa-4,5-carboxyphthalocyanine tetraanhydride hydroxyaluminum complex；hydroxyaluminum octa-4,5-carboxyphthalocyanine tetraanhydride
• CAS: 873430-64-9
• 化学式: C₄₀H₉AlN₈O₁₃
• 分子量: 836.539
• InChiKey: WRBPTHNJLIORFX-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  牛磺酸 、 hydroxo(phthalocyanine-2,3:9,10:16,17:23,24-tetrakis(dicarboxanhydride))aluminium(III) 以 further solvent(s) 为溶剂， 以36%的产率得到[23,25,73,75,123,125,173,175-octaoxo-24,74,124,174-tetrakis(2-sulfoethyl)-24,25,74,75,124,125,174,175-octahydro-23H,73H,123H,173H-5,10,15,20-tetraazatetraisoindolo[5,6-b:5',6'-g:5'',6''-l:5''',6'''-q]porphyrinato]hydroxoaluminum(III)
  参考文献：
  名称：

  酞菁和相关化合物：XXXVIII。对称的牛磺酸和胆碱取代的酞菁的合成

  摘要：

  已经开发出用于合成一系列衍生自水溶性阴离子和阳离子八-4,5-羧基酞菁-牛磺酸和胆碱结合物的金属配合物的方法。

  DOI：

  10.1007/s11176-005-0100-x
• 作为产物：
  描述：

  (hydroxo)(tetrakis(4,5-dicarboxy)phthalocyaninato)aluminum(III) 在 乙酸酐 作用下， 以 neat (no solvent) 为溶剂， 以90%的产率得到hydroxo(phthalocyanine-2,3:9,10:16,17:23,24-tetrakis(dicarboxanhydride))aluminium(III)
  参考文献：
  名称：

  Phthalocyanines and Related Compounds: XXXVII. Synthesis of Covalent Conjugates of Carboxy-substituted Phthalocyanines with α-Amino Acids

  摘要：

  Methods of synthesis of covalent conjugates of metal complexes of octa-4,5-carboxy- and tetra-4-carboxyphthalocyanine, as well as of octa-6,7-carboxy-2,3-naphthalocyanine with alpha-amino acids, glycine and sarcosine, were developed and certain properties of the products were studied. The prepared conjugates are soluble in organic solvents and water.

  DOI：

  10.1023/b:rugc.0000030404.00492.d1

文献信息

• Phthalocyanines and Related Compounds: XL. Synthesis of β-Diethylaminoethyl-substituted Octa-4,5-carboxyphthalocyanine Tetraimides and Their Quaternary Salts
  作者：S. A. Mikhalenko、L. I. Solov'eva、E. A. Luk'yanets

  DOI：10.1007/s11176-005-0451-3

  日期：2005.9

  Cobalt, zinc, hydroxoaluminum, and iron complexes of N,N′,N″,N‴-tetrakis(β-diethylaminoethyl) phthalocyanine-2,3 : 9,10 : 16,17 : 23,24-tetrakis(dicarboxamide) were synthesized and were converted into the corresponding water-soluble quaternary salts by treatment with methyl iodide, methyl p-toluenesulfonate, diethyl and dimethyl sulfates, and trimethyl phosphate. The electronic absorption spectra of the quaternary salts indicated their considerable aggregation in aqueous solution; the degree of aggregation decreases in going to solutions in ethanol and disappears in DMSO.

  合钴、锌、氢氧铝和铁的N,N′,N″,N‴-四(β-二乙氨基乙基)酞菁-2,3:9,10:16,17:23,24-四(二羧酰胺)复合物被合成，并通过与碘甲烷、对甲苯磺酸甲酯、二乙基和二甲基硫酸盐以及三甲基磷酸酯的处理转化为相应的水溶性季铵盐。季铵盐的电子吸收光谱表明它们在水溶液中的聚集程度相当大；在乙醇溶液中聚集程度降低，并在DMSO中消失。
• Phthalocyanines and related compounds: XLIV. Synthesis of conjugates of phthalocyanines with rhodamines
  作者：V. M. Derkacheva、S. A. Mikhalenko、L. I. Solov’eva、V. I. Alekseeva、L. E. Marinina、L. P. Savina、A. V. Butenin、E. A. Luk’yanets

  DOI：10.1134/s1070363207060291

  日期：2007.6

  A series of conjugates of sulfo- and carboxy-substituted phthalocyanines with rhodamines were prepared, and their electronic absorption and luminescence spectra were studied. An intramolecular transfer of the excitation energy from the rhodamine moiety (donor) to the phthalocyanine moiety (acceptor) was revealed.