dicarbonylcyclopentadienyl(p-fluorophenyl)iron | 31781-18-7

• 英文名称: dicarbonylcyclopentadienyl(p-fluorophenyl)iron
• 英文别名: (η5-C5H5)Fe(CO)2(C6H4F-p)；[CpFe(CO)2(4-FC6H4)]；CpFe(C6H4F-4)(CO)2
• CAS: 31781-18-7
• 化学式: C₁₃H₉FFeO₂
• 分子量: 272.059
• InChiKey: HPNOOSWOVCNMNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4-chloro-N-sulfinyl-benzenesulfonamide 、 dicarbonylcyclopentadienyl(p-fluorophenyl)iron 以 氯仿 为溶剂， 以50-80的产率得到η5-Fe(CO)2[N[S(O)-p-C6H4F][S(O)2-p-C6H4Cl]]
  参考文献：
  名称：

  Severson, Roland G.; Leung, Tak Wai; Wojcicki, Andrew, Inorganic Chemistry, 1980, vol. 19, # 4, p. 915 - 923

  摘要：

  DOI：
• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 以 not given 为溶剂， 生成 dicarbonylcyclopentadienyl(p-fluorophenyl)iron
  参考文献：
  名称：

  Arylation of Styrenes with Aryliron Complexes [CpFe(CO)₂Ar]

  摘要：

  Treatment of aryliron complexes [CpFe(CO)(2)Ar] with styrenes in boiling xylene affords the corresponding stilbenes. The aryliron complexes, which become active upon heating, serve as arylating agents in the reaction.

  DOI：

  10.1021/om1001952

文献信息

• Synthesis of Aryliron Complexes by Palladium-Catalyzed Transmetalation between [CpFe(CO)₂I] and Aryl Grignard Reagents and Their Chemistry Directed toward Organic Synthesis
  作者：Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om800560m

  日期：2008.8.1

  Palladium-catalyzed transmetalation between [CpFe(CO)2I] and aryl Grignard reagents emerges as a new method for the synthesis of [CpFe(CO)2Ar]. The aryliron complexes thus formed are useful arylmetal reagents that become active upon oxidation or UV irradiation.

  钯催化[CpFe（CO）2 I]与芳基格氏试剂之间的金属转移反应是一种合成[CpFe（CO）2 Ar]的新方法。如此形成的芳基铁配合物是有用的芳基金属试剂，其在氧化或紫外线照射下具有活性。
• A kinetic study of the cleavage of the ironcarbon σ bond in η5-C5H5Fe(CO)2R by halogenated acetic acids
  作者：Nancy De Luca、Andrew Wojcicki

  DOI：10.1016/s0022-328x(00)90296-1

  日期：1980.7

  The rates of the reaction of η5-C5H5Fe(CO)2R (R = alkyl and aryl) with CF3CO2H to give η5-C5H5Fe(CO)2OC(O)CF3 and RH wre investigated in organic solvents, mostly at 25°C, by infrared spectroscopic, manometric and volumetric techniques. When R = alkyl, the cleavage in CH2Cl2 is first order in η5-C5H5Fe(CO)2R and first order in the CF3CO2H monomer at acid concentrations ⪆0.1M, but first order in η5-C5H5Fe(CO)2R

  η的反应速率5 -C 5 H ^ 5的Fe（CO）2 R（R =烷基和芳基）与CF 3 CO 2小时，得到η 5 -C 5 H ^ 5的Fe（CO）2 OC（O） CF 3和RH通过红外光谱法，测压法和体积法在有机溶剂中（主要在25°C下）进行了研究。当R =烷基，CH裂解2氯2是在η一阶5 -C 5 H ^ 5的Fe（CO）2 R和第一级在CF 3 CO 2在酸浓度ħ单体⪆0.1中号在η，但一阶5 -C 5 H ^ 5的Fe（CO）2在CF R和二阶3 CO 2在较低酸浓度ħmonemer。二级速率常数对R的依赖性遵循C 5 H 5 > CH 5 Si（CH 3）3（> 110）> CH 3（32）> nC 4 H 9（15）> C 2 H 5的顺序（11）> CH 2 C（CH 3）3（6.2）> CH 2CH 2 C 6 H 5（5.3）> CH（CH 3）C 6 H 5（〜1.2）⪆CH
• Reactions of cyclopentadienylmetal-2-alkenyl carbonyl complexes with sulfur dioxide. Isolation and characterization of metal—η2-alkenesulfinate intermediates
  作者：R.L. Downs、A. Wojcicki

  DOI：10.1016/s0020-1693(00)87267-9

  日期：1978.1

  The isolation and characterization of the 2-alkene-S-sulfinato products of the reactions of transition metal-2-alkenyl complexes η5-C5H5M(CO)xCH2C(R)CR′R″ (M = Fe and x = 2, M = Mo and x = 3, M = W and x = 3; R = R′ = R″ = H, R = R′ = H and R″ = CH3, R = H and R′ = R″ = CH3, R = R′ = H and R″ = C6H3, R = CH3 and R′ = R″ = H, and/or R = R′ = H and R″ = Cl) with SO2 under a variety of conditions are

  过渡金属-2-烯基配合物η5-C5H5M（CO）x C（R）CR'R''（M = Fe and x = 2，M = Mo and x = 3，M = W and x = 3; R = R′= R''= H，R = R′= H且R''= CH3，R = H且R′= R''= ，R描述了在各种条件下用SO 2 ＝ R′＝ H且R″ ＝ C 6 H 3，R ＝ CH 3且R′＝ R″ ＝ H，和/或R ＝ R′＝ H且R″ ＝ Cl）。包含1,3重排的MS（O）2C（R'）（R''）C（R）CH2和/或未重排的MS（O）2 C（R）CR'R''烯丙基片段的产物是由不对称的2-烯基配合物获得。另外，某些金属2-烯烃-S-亚磺酸盐表现出与烯丙基CC键有关的顺-反异构现象。通过使用M = Fe而不是M = Mo或低温纯净的SO2可以促进重排S-磺胺基异构体的形成，此外，随着取代基
• Effective Transmetalation from Gold to Iron or Ruthenium
  作者：A. Stephen K. Hashmi、Lise Molinari

  DOI：10.1021/om200360q

  日期：2011.7.11

  The transmetalation of aryl, alkynyl, and alkyl groups from organogold compounds to iron complexes offers an efficient synthesis of organoiron complexes under very mild conditions. This method could be extended to ruthenium complexes.

  芳基，炔基和烷基基团从有机金化合物到铁配合物的金属转移，可以在非常温和的条件下有效地合成有机铁配合物。该方法可以扩展到钌配合物。
• Synthesis of Functionalized Aryliron Complexes [CpFe(CO)₂Ar] by Copper-Mediated Transmetalation between [CpFe(CO)₂I] and Aryltin Reagents
  作者：Shigeo Yasuda、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/om900964e

  日期：2010.1.11

  Transmetalation between [CpFe(CO)(2)I] and aryltin reagents in the presence of copper salts yields the corresponding aryliron complexes [CpFe(CO)(2)Ar]. The high functional group compatibility of this copper-mediated reaction enables us to obtain [CpFe(CO)AI having an acetyl or formyl group, which cannot be prepared by the previous methods with arylzinc or arylboron reagents under palladium catalysis.