[(η5-C5Me5)RuCl2(S2CO(i)Pr)] | 918828-87-2

• 英文名称: [(η5-C5Me5)RuCl2(S2CO(i)Pr)]
• 英文别名: [η5-C5Me5Ru(IV)Cl2(S2CO(i)Pr)]
• CAS: 918828-87-2
• 化学式: C₁₄H₂₂Cl₂ORuS₂
• 分子量: 442.436
• InChiKey: RLUMZWVNTKKRHZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η5-C5Me5)RuCl2(S2CO(i)Pr)] 、 tert-butylammonium hexafluorophosphate(V) 以 二氯甲烷 为溶剂， 生成 [η5-C5Me5Ru(V)Cl2(S2CO(i)Pr)]PF6
  参考文献：
  名称：

  Highly Oxidized Ruthenium Organometallic Compounds. The Synthesis and One-Electron Electrochemical Oxidation of [Cp*Ru^IVCl₂(S₂CR)] (Cp* = η⁵-C₅Me₅, R = NMe₂, NEt₂, OⁱPr)

  摘要：

  [Cp*(RuCl2)-Cl-IV(S2CR)] (R = NMe2, NEt2, and (OPr)-Pr-i) were synthesized by the reaction of [Cp*(RuCl2)-Cl-III](2) with [RC(S)S](2). One-electron electrochemical oxidation of [Cp*RuCl2(S2CR)] produces paramagnetic [Cp*RuCl2(S2CR)](+), which are stable in CH2Cl2 solution for at least several hours at 233 K. EPR experiments performed at 293 K show isotropic signals (g approximate to 2.035) with clearly defined hyperfine coupling to Ru-99 and Ru-101 of 25 G and with peak-to-peak line widths of 15 G. At temperatures below 153 K, axial-shaped EPR spectra were obtained with g-values close to 2 (2.050-2.008) and narrow peak-to-peak line widths ( 15 G). Results from DFT calculations indicate that approximately 70% of the spin density in [Cp*RuCl2(S2CNMe2)](+) is located on the ruthenium, although there is an increase of only 0.06 in the positive charge of the metal ion as a result of the oxidation. The high spin density on Ru supports the assignment of a formally Ru( V) oxidation state, which is unprecedented in organometallic chemistry. Chemical oxidation of Cp*(RuCl2)-Cl-IV(S2CNMe2) with NO(PF6) in CH3CN resulted in the isolation of [Cp*Ru-IV(MeCN)(2)(S2CNMe2)](+) 2 (4), while oxidation with [(4-Br-C6H4)(3)N](SbCl6) in CH2Cl2 resulted in the formation of chloro-bridged dimeric [Cp*(RuCl)-Cl-IV(S2CNMe2)](2)(+2) (5). When 5 is dissolved in CD3-CN/ CH3CN, it immediately converts to 4. Cyclic voltammetric experiments confirmed that in both solvents the chemical oxidation process occurred through the [Cp*(RuCl2)-Cl-V(S2CNMe2)](+) intermediate.

  DOI：

  10.1021/om060866z
• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)] 、 二硫化二异丙基黄原酸酯 以 乙腈 为溶剂， 生成 [(η5-C5Me5)RuCl2(S2CO(i)Pr)]
  参考文献：
  名称：

  Highly Oxidized Ruthenium Organometallic Compounds. The Synthesis and One-Electron Electrochemical Oxidation of [Cp*Ru^IVCl₂(S₂CR)] (Cp* = η⁵-C₅Me₅, R = NMe₂, NEt₂, OⁱPr)

  摘要：

  [Cp*(RuCl2)-Cl-IV(S2CR)] (R = NMe2, NEt2, and (OPr)-Pr-i) were synthesized by the reaction of [Cp*(RuCl2)-Cl-III](2) with [RC(S)S](2). One-electron electrochemical oxidation of [Cp*RuCl2(S2CR)] produces paramagnetic [Cp*RuCl2(S2CR)](+), which are stable in CH2Cl2 solution for at least several hours at 233 K. EPR experiments performed at 293 K show isotropic signals (g approximate to 2.035) with clearly defined hyperfine coupling to Ru-99 and Ru-101 of 25 G and with peak-to-peak line widths of 15 G. At temperatures below 153 K, axial-shaped EPR spectra were obtained with g-values close to 2 (2.050-2.008) and narrow peak-to-peak line widths ( 15 G). Results from DFT calculations indicate that approximately 70% of the spin density in [Cp*RuCl2(S2CNMe2)](+) is located on the ruthenium, although there is an increase of only 0.06 in the positive charge of the metal ion as a result of the oxidation. The high spin density on Ru supports the assignment of a formally Ru( V) oxidation state, which is unprecedented in organometallic chemistry. Chemical oxidation of Cp*(RuCl2)-Cl-IV(S2CNMe2) with NO(PF6) in CH3CN resulted in the isolation of [Cp*Ru-IV(MeCN)(2)(S2CNMe2)](+) 2 (4), while oxidation with [(4-Br-C6H4)(3)N](SbCl6) in CH2Cl2 resulted in the formation of chloro-bridged dimeric [Cp*(RuCl)-Cl-IV(S2CNMe2)](2)(+2) (5). When 5 is dissolved in CD3-CN/ CH3CN, it immediately converts to 4. Cyclic voltammetric experiments confirmed that in both solvents the chemical oxidation process occurred through the [Cp*(RuCl2)-Cl-V(S2CNMe2)](+) intermediate.

  DOI：

  10.1021/om060866z

文献信息

• Synthetic and X-ray Structural and Reactivity Studies of Cp*Ru^IV Complexes Containing Bidentate Dithiocarbonate, Xanthate, Carbonate, and Phosphinate Ligands (Cp* = η⁵-C₅Me₅)
  作者：Elaine Phuay Leng Tay、Seah Ling Kuan、Weng Kee Leong、Lai Yoong Goh

  DOI：10.1021/ic061781t

  日期：2007.2.19

  The reaction of [Cp*RuCl2](2) (1; Cp* = eta(5)-C5Me5) with tetraalkyldithiuram disulfides (R2NC(S)SS(S)CNR2, R = Me, Et), isopropylxanthic disulfide ([(PrOC)-Pr-i(S)S](2)), and bis(thiophosphoryl) disulfide ([((PrO)-Pr-i)(2)P(S)S](2)) led to the isolation of dark-red crystalline solids of Cp*(RuCl2)-Cl-IV(eta(2)-dithiolate) complexes [dithiolate = S2CNR2, DTCR (2a, R = Me; 2b, R = Et), (S2COPr)-Pr-i (3), and S2P((PrO)-Pr-i)(2) (4)]. Dichlorido substitution in 2 and 3 with DTCEt and (S2COPr)-Pr-i anions yielded Ru-IV derivatives containing bis(DTC) and mixed DTC-dithiocarbonate ligands. These are the first organoruthenium complexes of such ligands. The reaction of monophosphines with 2a resulted in monochlorido substitution, whereas the analogous reaction with 3 resulted in displacement of both chlorido ligands and reduction of the metal center to Ru-II. Reduction at Ru was also observed in the reaction of 2a with [CpCr(CO)(3)](2). Of these complexes, only 2 and 3 are air-stable in the solid state for an extended period. All of the complexes have been spectrally characterized, and selected compounds are also crystallographically characterized.