| 82489-52-9

• CAS: 82489-52-9
• 化学式: C₁₄H₁₁FeNO₄
• 分子量: 313.093
• InChiKey: RVIHJBFDAWUDNH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 2-异氰基-1,3,5-三甲基苯 在 cobalt(II) chloride hexahydrate 作用下， 以 苯 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Albers, Michel O.; Coville, Neil J.; Singleton, Eric, Journal of the Chemical Society, Dalton Transactions, 1982, p. 1069 - 1080

  摘要：

  DOI：
• 作为产物：
  描述：

  五羰基铁 、 2-异氰基-1,3,5-三甲基苯 在 cobalt(II) chloride hexahydrate 作用下， 以 苯 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Albers, Michel O.; Coville, Neil J.; Singleton, Eric, Journal of the Chemical Society, Dalton Transactions, 1982, p. 1069 - 1080

  摘要：

  DOI：

文献信息

• The preparation and spectra of [Fe2(η-C5H5)2(CO)4−n(CNAr)n] complexes. The reaction of [Fe(CO)5−m(CNAr)m] with dicyclopentadiene
  作者：A.R. Manning、Gerard McNally、Paul Soye

  DOI：10.1016/s0020-1693(00)83073-x

  日期：1991.2

  The relatively elusive [Fe2(eta-C5H5)2(CO)4-n(CNAr)n] complexes where n = 1 or 2 and Ar = C6H5, 2-MeC6H4, 4-MeC6H4, 2,4-Me2C6H3, 2,6-Me2C6H3 and 2,4,6-Me3C6H2 have been prepared by two effective, but not completely general routes. One is the light-catalyzed substitution of [Fe2(eta-C5H5)2(CO)4] by ArNC which gives the derivatives where n = 1 or 2 and, eventually, 4. The other is the reaction at 145-degrees-C of dicyclopentadiene with [Fe(CO)5] and ArNC or with [Fe(CO)4(CNAr)], but not with [Fe(CO)3(CNAr)2] or [Fe(CO)4(CNMe)]. The pathway of the reaction of dicyclopentadiene with [Fe(CO)5]or[Fe(CO)4(CNAr)] is discussed and it is concluded that it does not proceed via cyclopentadine and mononuclear cyclopentadienyl complexes but via species containing dicyclopentadiene and two metal atoms which are formed at an early stage in the reaction and which remain associated throughout the reaction up to the formation of the [Fe2(eta-C5H5)2(CO)4-n(CNAr)n] derivatives. The infrared and H-1 NMR spectra of the complexes are reported and discussed.