(Fe(η5-C5H5)(η5-C5H4PPh2))Ni(CO)3 | 1232828-44-2

• 英文名称: (Fe(η5-C5H5)(η5-C5H4PPh2))Ni(CO)3
• 英文别名: (FcPPh2)Ni(CO)3
• CAS: 1232828-44-2
• 化学式: C₂₅H₁₉FeNiO₃P
• 分子量: 512.935
• InChiKey: NNMOKKNVPYVKDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二苯基膦基二茂铁 、 (Fe(η5-C5H5)(η5-C5H4PPh2))Ni(CO)3 以 petroleum ether 为溶剂， 以37%的产率得到(Fe(η5-C5H5)(η5-C5H4PPh2))2Ni(CO)2
  参考文献：
  名称：

  Ferrocenyl phosphane nickel carbonyls: Synthesis, solid state structure, and their use as catalysts in the oligomerization of ethylene

  摘要：

  The synthesis of diverse ferrocenyl phosphane nickel carbonyls of type (FcPPh(2))Ni(CO)(3) (3), (FcPPh(2))(2)Ni(CO)(2) (4), fc(PR2Ni(CO)(3))(2) (R = Ph (6a), R = p-tolyl (6b)), and (fc(PPh2)(2)) Ni(CO)(2) (7) (eta(5)-C5H5)(eta(5)-C5H4)Fe, fc = (eta(5)-C5H4)(2)Fe) starting from FcPPh(2) (1), fc(PR2)(2) (R = Ph (5a); R = p-tolyl (5b)), and Ni(CO)(4) (2) is described. The structures of 3, 4, 6b, and 7 in the solid state are reported, intermolecular interactions by pi-pi-contacts are discussed. The behavior of 3, 4, 6a, 6b, and 7 towards the oligomerization of ethylene is reported. All compounds, except 4, were found to be inactive in homogeneous ethylene oligomerization, while they exhibit moderate activities (up to 660 kg prod/mol Ni h) in heterogeneous ethylene oligomerization experiments. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.012
• 作为产物：
  描述：

  二苯基膦基二茂铁 、 tetracarbonyl nickel 以 petroleum ether 为溶剂， 以80%的产率得到(Fe(η5-C5H5)(η5-C5H4PPh2))Ni(CO)3
  参考文献：
  名称：

  Ferrocenyl phosphane nickel carbonyls: Synthesis, solid state structure, and their use as catalysts in the oligomerization of ethylene

  摘要：

  The synthesis of diverse ferrocenyl phosphane nickel carbonyls of type (FcPPh(2))Ni(CO)(3) (3), (FcPPh(2))(2)Ni(CO)(2) (4), fc(PR2Ni(CO)(3))(2) (R = Ph (6a), R = p-tolyl (6b)), and (fc(PPh2)(2)) Ni(CO)(2) (7) (eta(5)-C5H5)(eta(5)-C5H4)Fe, fc = (eta(5)-C5H4)(2)Fe) starting from FcPPh(2) (1), fc(PR2)(2) (R = Ph (5a); R = p-tolyl (5b)), and Ni(CO)(4) (2) is described. The structures of 3, 4, 6b, and 7 in the solid state are reported, intermolecular interactions by pi-pi-contacts are discussed. The behavior of 3, 4, 6a, 6b, and 7 towards the oligomerization of ethylene is reported. All compounds, except 4, were found to be inactive in homogeneous ethylene oligomerization, while they exhibit moderate activities (up to 660 kg prod/mol Ni h) in heterogeneous ethylene oligomerization experiments. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.03.012