Synthesis and Characterization of the Tetrafluoridochlorates(III)
<i>A</i>
[ClF
<sub>4</sub>
] (
<i>A</i>
= K, Rb, Cs)
作者:Benjamin Scheibe、Sergei I. Ivlev、Antti J. Karttunen、Florian Kraus
DOI:10.1002/ejic.202000106
日期:2020.4.16
Single-crystalline tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs) were synthesized from solvolysis reactions of alkali metal fluorides in liquid chlorine trifluoride. The structures were examined by means of single-crystal X-ray diffraction. K[ClF4] crystallizes in the K[BrF4] structure type, whereas the Rb and Cs compounds crystallize in the Li[AuF4] structure type.
Solvolysis Reactions in Chlorine Trifluoride and Bromine Pentafluoride: Preparation of the Tetrafluorochlorates and Hexafluorobromates of Potassium, Rubidium, and Cesium
作者:E. Dow. Whitney、Richard O. MacLaren、Charles E. Fogle、Thomas J. Hurley