Infrared Spectra of OMCO (M = Cr−Ni), OMCO<sup>-</sup> (M = Cr−Cu), and MCO<sub>2</sub><sup>-</sup> (M = Co−Cu) in Solid Argon
作者:Mingfei Zhou、Binyong Liang、Lester Andrews
DOI:10.1021/jp984439d
日期:1999.4.1
Laser-ablated late transition metal atoms Cr through Ni react with CO2 molecules to give the insertion products OMCO, which have been isolated in solid argon. The insertion OMCO- molecular anions (Cr through Cu) were formed by electron capture and/or reaction with CO2-, and the addition MCO2- anions (M = Co, Ni, Cu) were produced by direct react:ion with CO2-. The excellent agreement between the observed frequencies and isotopic frequency ratios with those calculated by density functional theory supports these assignments.
SATO TAKAYORI; OKAMOTO SHOICHI; HASHIMOTO KOSHIRO, J. CERAM. SOC. JAP., 94,(1986) N 12, 1201-1205