neodymium(III) orthovanadate | 13721-46-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 镧系含氧阴离子化合物
• 英文名称: neodymium(III) orthovanadate
• 英文别名: neodymium vanadate；neodymium orthovanade；Nd orthovanadate；neodymium orthovanadate；Nd-vanadate(V)；neodymium(3+);trioxido(oxo)vanadium
• CAS: 13721-46-5
• 化学式: Nd*O₄V
• 分子量: 259.179
• InChiKey: SEEUVPGHIZOZOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.69
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  calcium orthovanadate 、 neodymium(III) orthovanadate 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Leonidov; Leonidova; Surat, Russian Journal of Inorganic Chemistry, 2001, vol. 46, # 2, p. 268 - 273

  摘要：

  DOI：
• 作为产物：
  描述：

  五氧化二钒 、 Neodymium Oxide Powder, 99.9% (REO) Nano 生成 neodymium(III) orthovanadate
  参考文献：
  名称：

  Détermination des chaleurs de formation des orthovanadates de certains éléments des terres rares par la méthode d'analyse thermique différentielle

  摘要：

  DOI：

  10.1007/bf01928431

文献信息

• Oxidative dehydrogenation of propane over rare-earth orthovanadates
  作者：Chak-Tong Au、Wei-De Zhang

  DOI：10.1039/a607565g

  日期：——

  High-purity rare-earth orthovanadates (R E VO 4 ), PrVO 4 , GdVO 4 , DyVO 4 , HoVO 4 , ErVO 4 , NdVO 4 , TbVO 4 and LuVO 4 , have been prepared by the citrate method. XRD, FTIR, LRS, UV–VIS diffuse reflectance, TPR and EPR techniques have been employed to characterize them. The catalytic performances of PrVO 4 , ErVO 4 , GdVO 4 , DyVO 4 and NdVO 4 in the oxidative dehydrogenation of propane can compete with that of Mg 3 V 2 O 8 . The selectivity of propene over TbVO 4 , LuVO 4 and HoVO 4 was relatively low. TPR results showed that the more easily the catalyst is reduced, the higher the propene selectivity. EPR and in situ Raman experiments confirmed the presence of low-valence vanadates at the catalyst surface in the reaction process. We observed that 18 O 2 -isotope exchange occurred over the catalysts via a double-step single exchange process and the activity of the catalysts increased with an increase of isotope exchange rate.

  高纯度稀土正钒酸盐 (R E VO₄)，包括 PrVO₄、GdVO₄、DyVO₄、HoVO₄、ErVO₄、NdVO₄、TbVO₄ 和 LuVO₄，已通过柠檬酸盐法制备。使用了XRD、FTIR、LRS、UV–VIS漫反射、TPR和EPR等技术对其进行了表征。PrVO₄、ErVO₄、GdVO₄、DyVO₄ 和 NdVO₄ 在丙烷的氧化脱氢反应中的催化性能可以与 Mg₃V₂O₈ 竞争。而 TbVO₄、LuVO₄ 和 HoVO₄ 的丙烯选择性相对较低。TPR结果表明，催化剂越容易被还原，丙烯选择性越高。EPR和原位拉曼实验证实了反应过程中催化剂表面存在低价钒酸盐。我们观察到，18O₂同位素交换在催化剂上通过双步单交换过程发生，催化剂的活性随着同位素交换速率的增加而提高。
• The general synthesis and characterization of rare earth orthovanadate nanocrystals and their electrochemical applications
  作者：Minyoung Yi、Seung-Keun Park、Chae-Yong Seong、Yuanzhe Piao、Taekyung Yu

  DOI：10.1016/j.jallcom.2016.09.249

  日期：2017.2

  Abstract We report a novel, simple synthetic route to uniform and highly crystalline rare earth orthovanadate (LnVO 4 , Ln = Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er, or Y) nanocrystals prepared through the reaction between Ln(III)-acetate and a vanadyl sulfate aqueous solution in xylene in the presence of surfactants. In the presented synthesis, vanadyl sulfate was introduced as a new vanadate source to

  摘要 我们报道了一种新颖、简单的合成路线，通过以下反应制备均匀且高度结晶的稀土原钒酸盐（LnVO 4 ，Ln = Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Er 或 Y）纳米晶体在表面活性剂的存在下，Ln(III)-乙酸盐和二甲苯中的硫酸氧钒水溶液。在所提出的合成中，引入了硫酸氧钒作为新的钒酸盐源来控制反应速率，从而在温和的反应条件下形成高度结晶的 LnVO 4 纳米晶体。通过将Ln 源从Ce 改为Er，可以很容易地控制LnVO 4 纳米晶体的形态，从长纳米棒到短纳米棒和纳米盘。
• An investigation of the high temperature reaction of the alkali metal metavanadates MVO3 (M=Na, K) with the lanthanide oxides Ln2O3 (Ln=Nd, Er)
  作者：D. de Waal、A.M. Heyns、K.-J. Range

  DOI：10.1016/0025-5408(91)90126-7

  日期：1991.11

  Abstract The changes occurring in the dielectric constant of an alkali metal metavanadate after it has been treated at high temperatures with a small percentage of a lanthanide oxide were previously ascribed to solid solution formation [R.T. Patil, N.B. Patil, A.P. Kashid and S.H. Shavan, Mat. Res Bull. 25 , 57 (1990).]. Analysis of the products obtained by means of Raman spectroscopy, X-ray powder

  摘要 碱金属偏钒酸盐在高温下用少量镧系元素氧化物处理后介电常数发生的变化先前归因于固溶体形成 [RT Patil, NB Patil, AP Kashid 和 SH Shavan, Mat . 水牛。25, 57 (1990).]。然而，通过拉曼光谱、X 射线粉末衍射、SEM 和 EDX 分析获得的产物的分析表明，在偏钒酸盐块中形成了少量的镧系元素原钒酸盐。发生的反应可用以下方程式描述：2 MVO 3 + Ln 2 O 3 2 LnVO 4 + M 2 O。在真空条件下使用化学计量的试剂完全转化为镧系元素原钒酸盐。
• Simulation of the energy level scheme of Nd³⁺and Eu³⁺ions in rare-earth orthovanadates and phosphates
  作者：E Antic-Fidancev、J Holsa、M Lemaitre-Blaise、P Porcher

  DOI：10.1088/0953-8984/3/35/012

  日期：1991.9.2

  the aid of the measured Raman scattering spectra of LaVO4:Nd3+ and NdVO4. Based on the energy level schemes derived from the absorption and luminescence spectra the parametrization of the free-ion and crystal-field effects were carried out with good results as indicated by the low RMS deviation values. The parameter sets for Nd3+ and Eu3+ ions in the same matrices are consistent with each other but no

  测量了四方磷钇矿型NdVO4和单斜独居石型LaVO4、LaPO4和NdPO4中Nd3+离子的吸收光谱以及LaVO4和LaPO4中Eu3+离子的发光，并根据下式对光谱进行了分析。 RE站点的适当对称性。除了纯零声子电子线之外，Nd3 + 离子的吸收光谱显示出广泛的振动边带，借助测量的 LaVO4：Nd3 + 和 NdVO4 的拉曼散射光谱进行识别。基于从吸收光谱和发光光谱得出的能级方案，自由离子和晶体场效应的参数化进行了良好的结果，如低 RMS 偏差值所示。
• Design of Neodymium Vanadate Nanoparticles Decorated on Carbon–Boron Core-Shell Microspheres Matrix: An Electrochemical Detection of Nilutamide
  作者：Sriram Balasubramanian、Jeena N. Baby、Yung-Fu Hsu、Sea-Fue Wang、Mary George

  DOI：10.1149/1945-7111/ac82ce

  日期：2022.8.1

  The risk of pharmaceutical contamination is a growing ecological issue that affects every region of the globe. Continuous enhancement in the intake and negligent domestic ejection of these cytostatic agents are the main grounds for the occurrence of active residual metabolites in various aquatic environments. Electrochemical sensors are a capable substitute for other conventional analytical methods for monitoring toxic drug pollutants due to their beneficial features. Thus, the purpose of this work is to demonstrate an energy-efficient fabrication of neodymium vanadate integrated with boron-doped carbon (NdVO₄/B–C) hybrid composite for the selective electrochemical determination of nilutamide (NT– anti-androgen drug). The choice of neodymium among rare earth metals has a significant impact on the electrochemical redox processes. In addition, rapid electron mobility for well-separated peaks and defined current potentials implies an improved active surface area in NdVO_4. Therefore, the incorporation of B–C displays substantial enhancement in electronic conductivity, identifying the nanocomposite as a remarkable detecting candidate. The presence of multiple oxidation states of rare earth vanadate embedded on boron-doped activated carbon results in high synergistic interactions and advanced matrix structures that facilitate superlative electrocatalytic characteristics including the minimal R_ct value (81.32 Ω.cm²), wide linear-range responses (0.001–344 μM), low limit of detection (0.0002 μM), high sensitivity (5.56 μA·μM⁻¹·cm⁻²), good stabilities (operational stability = 3000 s and storage stability = 20 days), and excellent selectivity (with an excess concentration of 12 interfering compounds). It is noteworthy that the NdVO₄/B–C modified electrode provides an outstanding recovery range (±99.91%–99.94%) for real sample analysis, thus marking it to be a competitive sensor option for commercial usage.

  制药污染风险是一个日益增长的生态问题，影响全球每个地区。这些细胞毒素的摄入和粗心的家庭排放是各种水生环境中活性残留代谢物出现的主要原因。由于其有益特性，电化学传感器是监测有毒药物污染物的一种有能力的替代传统分析方法。因此，本文旨在展示一种节能的钕钒酸盐与掺硼碳（NdVO₄/B-C）混合复合材料的制备方法，用于选择性电化学测定尼鲁替胺（NT-抗雄激素药物）。在稀土金属中选择钕对电化学氧化还原过程有重要影响。此外，良好分离峰和定义电流电位的快速电子迁移意味着NdVO₄具有改进的活性表面积。因此，掺硼碳的加入显示出电子导电性的显著提高，将纳米复合材料确定为一个显著的检测候选者。稀土钒酸盐的多种氧化态嵌入掺硼活性炭中，导致高协同作用和先进的矩阵结构，促进了卓越的电催化特性，包括最小的R_ct值（81.32 Ω·cm²），广泛的线性范围响应（0.001-344 μM），低检测限（0.0002 μM），高灵敏度（5.56 μA·μM^-1·cm^-2），良好的稳定性（操作稳定性=3000 s，储存稳定性=20天）和优异的选择性（与12种干扰化合物的过量浓度）。值得注意的是，NdVO₄/B-C修饰电极为实际样品分析提供了一个出色的恢复范围（±99.91%-99.94%），因此标志着它是一个竞争性的传感器选项用于商业使用。