thiosulfuric acid S-(6-amino-hexyl ester) | 21679-18-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代硫酸及其衍生物
• 英文名称: thiosulfuric acid S-(6-amino-hexyl ester)
• 英文别名: 1-Amino-6-sulfomercapto-hexan；Thioschwefelsaeure-S-(6-amino-hexylester)；1-HEXANETHIOL, 6-AMINO-, HYDROGEN SULFATE (ester)；1-amino-6-sulfosulfanylhexane
• CAS: 21679-18-5
• 化学式: C₆H₁₅NO₃S₂
• 分子量: 213.322
• InChiKey: FVAITYGYNLHBDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.2
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  114
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  thiosulfuric acid S-(6-amino-hexyl ester) 在 硫化氢 作用下， 生成 dithiobis(6-hexaneamine)
  参考文献：
  名称：

  Action of hydrogen sulfide on aminoalkanethiosulfuric acids (Bunte salts) to give di-, tri-, and tetrasulfides

  摘要：

  DOI：

  10.1021/jo00823a005
• 作为产物：
  描述：

  6-溴己基胺盐酸盐 在 sodium thiosulfate 作用下， 生成 thiosulfuric acid S-(6-amino-hexyl ester)
  参考文献：
  名称：

  潜在的抗辐射剂。I.伯氨基链烷硫基硫酸。

  摘要：

  DOI：

  10.1021/jm00303a600

文献信息

• PROCESS FOR PRODUCING AMINOALKYLTHIOSULFURIC ACID COMPOUND
  申请人：Ozturk Orhan

  公开号：US20130116468A1

  公开（公告）日：2013-05-09

  An aminoalkylthiosulfuric acid compound represented by formula (1): is produced. In step (A1), a hydrochloride of a chloroalkylamine compound represented by formula (2): is reacted with an alkali metal salt of thiosulfuric acid in the presence of 2 to 6 parts by weight of water with respect to 1 part by weight of the hydrochloride between 50° C. and 100° C. R 1 and R 2 each represents a hydrogen atom and the like, and n represents an integer of 2 to 9. In step (B1), a mixture of a solid containing the aminoalkylthiosulfuric acid compound and a liquid containing an alkali metal chloride is obtained by adjusting the temperature of the mixture of step (A1) to between −15° C. and 50° C. In step (C1), the aminoalkylthiosulfuric acid compound is obtained as solid by separating the solid containing the aminoalkylthiosulfuric acid compound and the liquid containing the alkali metal chloride from the mixture of (B1).

  通过公式（1）表示的一种氨基烷基硫酸化合物被生产。在步骤（A1）中，在50°C至100°C之间，将通过公式（2）表示的氯烷基胺化合物的盐酸与硫代硫酸盐的碱金属盐在1份盐酸的重量相对于2至6份水的存在下反应。R1和R2各代表氢原子等，n代表2至9的整数。在步骤（B1）中，通过将步骤（A1）的混合物的温度调整到-15°C至50°C之间，得到含有氨基烷基硫酸化合物的固体和含有碱金属氯化物的液体的混合物。在步骤（C1）中，通过将含有氨基烷基硫酸化合物的固体和含有碱金属氯化物的液体从（B1）的混合物中分离出来，得到氨基烷基硫酸化合物作为固体。
• METHOD FOR LOWERING DYNAMIC-TO-STATIC MODULUS RATIO OF VULCANIZED RUBBER
  申请人：Uekita Yasuo

  公开号：US20140142217A1

  公开（公告）日：2014-05-22

  A method for lowering the dynamic-to-static modulus ratio of vulcanized rubber, the method comprising a first step of kneading a rubber component, a filler and a compound represented by formula (I) or a salt thereof, a second step of kneading the kneaded mixture obtained in the first step, a sulfur component and a vulcanization accelerator, and a third step of thermally treating the kneaded mixture obtained in the second step, in formula (I), n represents an integer of 0 to 10. The compound represented by formula (I) or a salt thereof is preferably S-(3-aminopropyl)thiosulfuric acid or a salt thereof.

  一种降低硫化橡胶动态与静态模量比的方法，该方法包括第一步：将橡胶组分、填料和化合物(I)或其盐混合揉捏；第二步：将第一步所得到的混合物、硫组分和硫化促进剂混合揉捏；第三步：对第二步所得到的混合物进行热处理。在公式(I)中，n表示0到10的整数。化合物(I)或其盐最好是S-(3-氨基丙基)硫酸或其盐。
• TIRE MEMBER AND METHOD FOR MANUFACTURING THE SAME
  申请人：Toyo Tire & Rubber Co., Ltd.

  公开号：US20140128498A1

  公开（公告）日：2014-05-08

  A method for manufacturing a tire member, that improves various performances such as abrasion resistance, tear strength, fatigue resistance and the like of the tire member in good balance is provided. The method includes a step (A) for mixing at least a rubber component, a filler and a thiosulfuric acid compound containing an amino group, and a step (B) for mixing the mixture obtained by the step (A), a sulfur component, and a vulcanization accelerator, wherein the thiosulfuric acid compound containing an amino group is added in an amount of 0.2 parts by mass or more to 100 parts by mass of the rubber component in the step (A), and a temperature of the mixture during mixing is maintained within a range of from 145 to 170° C. for 20 seconds or more in the step (A).

  提供了一种制造轮胎零件的方法，该方法在良好平衡中提高了轮胎零件的耐磨性、撕裂强度、疲劳性能等各种性能。该方法包括步骤（A）混合至少一种橡胶组分、填料和含有氨基的硫代硫酸化合物，以及步骤（B）混合通过步骤（A）获得的混合物、硫组分和硫化促进剂。其中，含有氨基的硫代硫酸化合物在步骤（A）中以0.2质量部或更多的量添加到100质量部的橡胶组分中，并且在步骤（A）中混合时，混合物的温度在145至170℃范围内维持20秒或更长时间。
• METHOD FOR USING S-(3-AMINOPROPYL)THIOSULFURIC ACID AND/OR METAL SALT THEREOF
  申请人：Sumitomo Chemical Company Limited

  公开号：EP2589619A1

  公开（公告）日：2013-05-08

  A method for using S-(3-aminopropyl)thiosulfuric acid and/or a metal salt thereof added to a rubber component as a raw material of a vulcanized rubber composition, comprising a pre-kneading step A of kneading a rubber component, a filler, S-(3-aminopropyl)thiosulfuric acid and/or a metal salt thereof, a post-kneading step B of kneading the kneaded substance A obtained in the pre-kneading step A, a sulfur component, and a vulcanization accelerator having a weight over the weight of the above-described sulfur component, and a thermal treatment step C of thermally-treating the kneaded substance B obtained in the post-kneading step B to obtain a vulcanized rubber composition, wherein durability is imparted to the vulcanized rubber composition;

  一种使用添加到橡胶成分中的 S-(3-氨基丙基)硫代硫酸和/或其金属盐作为硫化橡胶组合物原料的方法，包括 捏合橡胶成分、填充剂、S-(3-氨基丙基)硫代硫酸和/或其金属盐的预捏合步骤 A、 后捏合步骤 B：捏合在预捏合步骤 A 中得到的捏合物 A、硫磺成分和硫化促进剂，硫化促进剂的重量超过上述硫磺成分的重量，以及 热处理步骤 C：对在后捏合步骤 B 中得到的捏合物 B 进行热处理，以得到硫化橡胶组合物，其中赋予硫化橡胶组合物耐久性；
• MANUFACTURING METHOD FOR AMINOALKYL THIOSULFURIC ACID COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2599772A1

  公开（公告）日：2013-06-05

  A process for producing an aminoalkylthiosulfuric acid compound represented by formula (1): wherein R1 and R2 each independently represent a hydrogen atom and the like, and n represents an integer of 2 to 9, the process comprising the following steps (A1), (B1) and (C1) : (A1) a step of reacting a hydrochloride of a chloroalkylamine compound represented by formula (2): wherein R1, R2 and n are as defined above, with an alkali metal salt of thiosulfuric acid in the presence of from 2 parts by weight to 6 parts by weight of water with respect to 1 part by weight of the hydrochloride of the chloroalkylamine compound represented by formula (2) at between 50ºC and 100ºC, (B1) a step of obtaining a mixture of a solid containing the aminoalkylthiosulfuric acid compound represented by formula (1) and a liquid containing an alkali metal chloride by adjusting the temperature of the reaction mixture obtained in step (A1) to not lower than -15ºC and lower than 50ºC, (C1) a step of obtaining the aminoalkylthiosulfuric acid compound represented by formula (1) as solid by separating the solid containing the aminoalkylthiosulfuric acid compound represented by formula (1) and the liquid containing the alkali metal chloride from the mixture obtained in step (B1).

  一种生产由式（1）代表的氨基烷基硫代硫酸化合物的工艺： 其中 R1 和 R2 各自独立地代表氢原子等，n 代表 2 至 9 的整数，该工艺包括以下步骤 (A1)、(B1) 和 (C1) ： (A1) 使式(2)代表的氯烷基胺化合物的盐酸盐反应的步骤： 其中 R1、R2 和 n 如上定义、 与硫代硫酸的碱金属盐在 2 份（重量）至 6 份（重量）水（相对于 1 份（重量） 式（2）代表的氯烷基胺化合物盐酸盐）的存在下，在 50ºC 至 100ºC 之间进行反应、 (B1) 通过将步骤(A1)中得到的反应混合物的温度调节至不低于-15ºC 和不低于 50ºC 的温度，得到含有式(1)代表的氨基烷基硫代硫酸化合物的固 体和含有碱金属氯化物的液体的混合物的步骤、 (C1) 从步骤(B1)得到的混合物中分离出含有式(1)代表的氨基烷基硫代硫酸化合物的固 体和含有碱金属氯化物的液体，得到式(1)代表的氨基烷基硫代硫酸化合物固体的步 骤。