Copper--neptunium (5/1) | 918441-32-4

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Copper--neptunium (5/1)
• 英文别名: copper;neptunium
• CAS: 918441-32-4
• 化学式: Cu₅Np
• 分子量: 554.778
• InChiKey: CTPIJQXYSFUKOS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  铜 、 镎 以 melt 为溶剂， 生成 Copper--neptunium (5/1)
  参考文献：
  名称：

  Highly correlated electron behavior in NpCu5−x(Pd,Ni)x—a contrast to UCu5−x(Pd,Ni)x

  摘要：

  We report the low-temperature specific heats of NpCu5-xPdx (x = 0, 0.5, 1.0, and 1.5), the "plus one f-electron" analogs to the well-studied non-Fermi liquid (nFl) system UCu5-xPdx. The Np materials were shown to form in the same AuBe5 structure type as the U pseudobinary alloys. A number of differences between the Np and U materials are found. The magnetic transition at 15 K in the U system is evidently suppressed to lower temperatures in the Np analog, and the low-temperature C/T values are strongly enhanced in the NpCU5-xPdx (x = 1.0 and 1.5) alloys vs. their U counterparts. Finally, NpCu4Ni appears to show non-Fermi liquid behavior similar to that of the NpCu5-xPdx system, just as UCu4M is quite similar to UCu4Pd in its nFl behavior. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.physb.2006.01.022