Dysprosium--palladium (1/1) | 39293-46-4

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间镧系化合物
• 英文名称: Dysprosium--palladium (1/1)
• 英文别名: dysprosium;palladium
• CAS: 39293-46-4
• 化学式: Dy₀Pd₀
• 分子量: 110.009
• InChiKey: PUIUEYOQKIWYHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.0
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Dysprosium--palladium (1/1) 、 氢气 在 H₂S 作用下， 生成
  参考文献：
  名称：

  Sinsel, Bernd; Anton, Herbert; Schmidt, Peter C., Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1998, vol. 102, # 4, p. 629 - 641

  摘要：

  DOI：
• 作为产物：
  描述：

  氢化镝(DyH3) 、 Palladium-Silver 生成 Dysprosium--palladium (1/1)
  参考文献：
  名称：

  Sinsel, Bernd; Anton, Herbert; Schmidt, Peter C., Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, 1998, vol. 102, # 4, p. 629 - 641

  摘要：

  DOI：

文献信息

• A Comparative Study of the Solubility and Thermodynamics of Hydrogen in Pd1-xREx (RE = Dy, Gd, Sm, and Y; x = 0.05 and 0.08) Solid Solution Alloys
  作者：Sundara Ramaprabhu、Natarajan Rajalakshmi、Alarich Weiss

  DOI：10.1002/bbpc.19890930608

  日期：1989.6

  AbstractPressure‐composition‐temperature absorption isotherms have been determined for the Pd1‐xREx (RE = Dy, Gd, Sm, and Y; x = 0.05 and 0.08) solid solution face centered cubic alloys in the pressure and temperature ranges 2 ≦ P(H2)/mbar ≦ 1000 and 473 ≦ T/K ≦ 873 using the manometric method. The partial molar enthalpy of solution of hydrogen at infinite dilution (ΔH̄0H) becomes more exothermic with increasing content of RE. The partial molar excess entropy of hydrogen solution at infinite dilution (ΔS̄E.0H) decreases with xRE. A correlation of the atomic diameter (dRE) of the substituting rare‐earth metals when in solution in palladium with ΔH̄0H and with the metal‐hydrogen interaction shows that the increase in the exothermicity of the Pd1‐xREx solid solution alloys is due to the lattice expansion and an attractive metal‐hydrogen interaction. From the correlation of ΔH̄0H with dRE of Pd1‐xREx (x = 0.05 and 0.075), ΔH̄0H of Pd1‐xREx (RE = Yb, Ho, and Eu; x = 0.05 and 0.075) solid solution alloys have been predicted. The dependence of ΔH̄0H of the “expanded” and “contracted” Pd1‐xMx alloys on the size of the octahedral interstitial hole sites (rh) occupied by hydrogen atoms is discussed.
• Sinsel, Bernd; Anton, Herbert; Schmidt, Peter C., Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, <hi>1998</hi>, vol. 102, # 4, p. 629 - 641
  作者：Sinsel, Bernd、Anton, Herbert、Schmidt, Peter C.、Weiden, Norbert、Weiss, Alarich

  DOI：——

  日期：——