Tb(cobalt)5 | 12017-69-5

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Tb(cobalt)5
• 英文别名: Cobalt;terbium；cobalt;terbium
• CAS: 12017-69-5
• 化学式: Co₅Tb
• 分子量: 453.891
• InChiKey: QZUXOPCKXSLKFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氢化铽 、 钴 以 neat (no solvent) 为溶剂， 生成 Tb(cobalt)5
  参考文献：
  名称：

  Rare-earth contributions to the x-ray magnetic circular dichroism at the CoKedge in rare-earth–cobalt compounds investigated by multiple-scattering calculations

  摘要：

  The x-ray magnetic circular dichroism (XMCD) has been measured at the Co K edge in hcp-Co and X-Co compounds (R = La,Tb,Dy). The structure of the experimental XMCD spectra in the near-edge region has been observed to be highly sensitive to the magnetic environment of the absorbing site. Calculations of the XMCD have been carried out at the Co K edge in Co metal, LaCo5, and TbCo5 within the multiple-scattering framework including the spin-orbit coupling. In the three systems, the XMCD spectra in the near-edge region are well reproduced. The possibility to separate the local effects from those due to the neighboring atoms in the XMCD cross section makes possible a more physical understanding of the spectra. The present results emphasize the major role played by the d states of the Tb ions in the XMCD spectrum at the Co K edge in the TbCo5 compound. [S0163-1829(98)04741-9].

  DOI：

  10.1103/physrevb.58.12271

文献信息

• Thermal expansion and spontaneous magnetostriction of RCo5 intermetallic compounds
  作者：A.V. Andreev、S.M. Zadvorkin

  DOI：10.1016/0921-4526(91)90011-3

  日期：1991.7

  Thermal expansion of RCo5 compounds (R = Pr, Nd, Sm, Gd, Tb, Dy, Ho) is investigated by X-ray diffractometry on single crystalline samples in the temperature range 5-1300 K. All compounds undergo large spontaneous magnetostrictive deformations, the volume effect reaches 3.2 x 10(-2) at 5 K in HoCo5.5. The contributions to the volume effect from Co-Co and R-Co exchange interactions are determined by comparison with YCo5, Y being the nonmagnetic analogue of R.
• Exchange interactions and magnetocrystalline anisotcopy of rare-earth—cobalt compounds with CaCu5-type structure
  作者：A. S. Ermolenko

  DOI：10.1002/pssa.2210590144

  日期：1980.5.16
• Magnetic properties of Tb1−xUxCo5 single crystals
  作者：A.V. Andreev

  DOI：10.1016/0925-8388(95)02155-8

  日期：1996.3

  U forms solid solutions in TbCo5 up to x = 0.6 with contraction of lattice in the basal plane and expansion along the c axis. The Curie temperature and the Co magnetic moment decrease with increasing U content. The interval of spin reorientation shifts to lower temperatures.
• Rare-earth contributions to the x-ray magnetic circular dichroism at the Co<b><i>K</i></b>edge in rare-earth–cobalt compounds investigated by multiple-scattering calculations
  作者：J. P. Rueff、R. M. Galéra、Ch. Giorgetti、E. Dartyge、Ch. Brouder、M. Alouani

  DOI：10.1103/physrevb.58.12271

  日期：——

  The x-ray magnetic circular dichroism (XMCD) has been measured at the Co K edge in hcp-Co and X-Co compounds (R = La,Tb,Dy). The structure of the experimental XMCD spectra in the near-edge region has been observed to be highly sensitive to the magnetic environment of the absorbing site. Calculations of the XMCD have been carried out at the Co K edge in Co metal, LaCo5, and TbCo5 within the multiple-scattering framework including the spin-orbit coupling. In the three systems, the XMCD spectra in the near-edge region are well reproduced. The possibility to separate the local effects from those due to the neighboring atoms in the XMCD cross section makes possible a more physical understanding of the spectra. The present results emphasize the major role played by the d states of the Tb ions in the XMCD spectrum at the Co K edge in the TbCo5 compound. [S0163-1829(98)04741-9].