Palladium--uranium (4/1) | 12412-97-4

• 分子结构分类: 无机化合物 - 均相金属化合物 - 金属间过渡金属化合物
• 英文名称: Palladium--uranium (4/1)
• 英文别名: palladium;uranium
• CAS: 12412-97-4
• 化学式: Pd₄U
• 分子量: 663.709
• InChiKey: SALHUIGWEUNTEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  铀 、 钯 以 neat (no solvent) 为溶剂， 生成 Palladium--uranium (4/1)
  参考文献：
  名称：

  Gibbs energy of formation of UPd4(s)

  摘要：

  Gibbs energies of formation of UPd4(s) have been determined by measuring the equilibrium CO(g) pressures over a UO2(s)+C(s)+ U0.15Pd0.85(s)+UPd4(s) mixture in the temperature range 1202 to 1306 K and are represented as: Delta(f)G(m)degrees(UPd4, s, T)+/-4.5 (kJ mol(-1)) = - 528.1 + 0.1223T (K) (1202 less than or equal to T (K) less than or equal to 1306). (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0925-8388(99)00237-6

文献信息

• Magnetic properties of the UPd4+x ( −0.25 ≤ x ≤ 0.2) system
  作者：M. Kontani、H. Hagiwara、T. Nishioka、H. Matsui、K. Adachi

  DOI：10.1016/s0304-8853(10)80193-3

  日期：1990.12

  We have performed magnetic susceptibility, electrical resistivity and specific heat measurements of UPd4+x (x = -0.25,0 and 0.2) and found that the magnetic properties of the system change drastically with x as well as annealing conditions: the antiferromagnetic ordering occurs at T(N) = 32 K for UPd4.2 but it almost disappears for UPd3.75.
• Gibbs energy of formation of UPd4(s)
  作者：R. Prasad、Smruti Dash、S.C. Parida、Ziley Singh、V. Venugopal

  DOI：10.1016/s0925-8388(99)00237-6

  日期：1999.8

  Gibbs energies of formation of UPd4(s) have been determined by measuring the equilibrium CO(g) pressures over a UO2(s)+C(s)+ U0.15Pd0.85(s)+UPd4(s) mixture in the temperature range 1202 to 1306 K and are represented as: Delta(f)G(m)degrees(UPd4, s, T)+/-4.5 (kJ mol(-1)) = - 528.1 + 0.1223T (K) (1202 less than or equal to T (K) less than or equal to 1306). (C) 1999 Elsevier Science S.A. All rights reserved.