| 1063737-46-1

• CAS: 1063737-46-1
• 化学式: C₃₈H₃₀Cl₂P₂PtS₂
• 分子量: 878.722
• InChiKey: GTTZQJORLWDHIN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 S2CC(PPh3)2 以 四氢呋喃 为溶剂， 以95%的产率得到
  参考文献：
  名称：

  The carbodiphosphorane–CS2 adduct as a complex ligand: Crystallographic characterization of [I2Pt{S2CC(PPh3)2}]·CH2Cl2, [Pt{S2CC(PPh3)2}2][SiF5]2·2CH2Cl2 and [(Me)2PtFI{S2CC(PPh3)2}]·2CH2Cl2

  摘要：

  The betain-like compound S2CC(PPh3)(2) (1), which is obtained from CS2 and the double ylide C(PPh3)(2), reacts with [X2Pt(COD)] (X = Cl, 1) in THF to afford the complexes [X2Pt{S2CC(PPh3)(2)}] (2, X = Cl; 3, X = 1) in quantitative yields. Both compounds are insoluble in all usual solvents, and 3 could be characterized by an X-ray analysis. For comparison, the structures of [Pt(Me)(2)FI{S2CC(PPh3)(2)}] center dot 2CH(2)Cl(2) (4 center dot 2CH(2)Cl(2)) with Pt-IV and [Pt{S2CC(PPh3)(2)}(2)][SiF5](2) center dot 2CH(2)Cl(2) (5 center dot 2CH(2)Cl(2)) with Pt-II are also presented. The compounds are further characterized by P-31 NMR and IR spectroscopy. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.05.003