Na(Cr(η5-C5H5)(CO)3)*2(1,2-dimethoxyethane) | 12203-12-2

• 英文名称: Na(Cr(η5-C5H5)(CO)3)*2(1,2-dimethoxyethane)
• 英文别名: NaCr(η5-C5H5)(CO)3*2(1,2-dimethoxyethane)
• CAS: 12203-12-2
• 化学式: 2C₄H₁₀O₂*C₈H₅CrO₃*Na
• 分子量: 404.356
• InChiKey: HGKXEQZFPLOCHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Na(Cr(η5-C5H5)(CO)3)*2(1,2-dimethoxyethane) 、 (C₆H₃-2,6-Trip₂)SnCl 以 甲苯 为溶剂， 以28%的产率得到[(η⁵-C₅H₅)(CO)₃Cr(SnC₆H₃-2,6-Trip₂)]
  参考文献：
  名称：

  的合成，结构，和Metallostannylenes的光谱（η 5 -C 5 H ^ 5）（CO）3 M-SN-C 6 H ^ 3 -2,6-的Ar 2（M =铬，钼，W;氩= C 6 H 2 -2,4,6-Me 3，C 6 H 2 -2,4,6-Pr i 3）

  摘要：

  所述metallostannylene化合物（η 5 -C 5 H ^ 5）（CO）3 MSnC 6 ħ 3 -2,6-MES 2（MES = C 6 H ^ 2 -2,4,6--ME 3 ; M =铬（1） ，钼（2），W（3）），（η 5 -C 5 H ^ 5）（CO）3 MSnC 6 ħ 3 -2,6-跳闸2（跳闸= C 6 H ^ 2 -2,4,6- Pr i 3 ; M = Cr（4），Mo（5），W（6）），和（η 5 -1,3-卜吨Ç 6 ħ 3）MoSnC 6 ħ 2 -2,6-跳闸2（7通过适当的aryltin的反应合成）（II）与环戊二烯基羰基金属盐的碱金属盐卤化。的化合物，其分离为紫色（1 - 6）或绿松石（7）晶体，在锡处是具有V形两坐标几何形状的单体。锡-过渡金属键比金属和共价半径预测的距离或在相关锡（IV）-过渡金属物种中观察到的距离稍长。还通过IR和UV-vis光谱以及1

  DOI：

  10.1021/om020583g
• 作为产物：
  描述：

  六羰基铬 、 cyclopentadienyl sodium*1,2-dimethoxyethane 以 乙二醇二甲醚 为溶剂， 以86%的产率得到Na(Cr(η5-C5H5)(CO)3)*2(1,2-dimethoxyethane)
  参考文献：
  名称：

  Bender, Robert; Braunstein, Pierre; Jud, Jean-Marc, Inorganic Chemistry, 1983, vol. 22, # 23, p. 3394 - 3407

  摘要：

  DOI：

文献信息

• Triple Bonding to Germanium:  Characterization of the Transition Metal Germylynes (η⁵-C₅H₅)(CO)₂M⋮Ge-C₆H₃-2,6-Mes₂ (M = Mo, W; Mes = −C₆H₂-2,4,6-Me₃) and (η⁵-C₅H₅)(CO)₂M⋮Ge-C₆H₃-2,6-Trip₂ (M = Cr, Mo, W; Trip = −C₆H₂-2,4,6-i-Pr₃) and the Related Single Bonded Metallogermylenes (η⁵-C₅H₅)(CO)₃M-G̈e-C₆H₃-2,6-Trip₂ (M = Cr, W)
  作者：Lihung Pu、Brendan Twamley、Scott T. Haubrich、Marilyn M. Olmstead、Benjamin V. Mork、Richard S. Simons、Philip P. Power

  DOI：10.1021/ja992937+

  日期：2000.2.1

  The synthesis and characterization of several m-terphenyl stabilized germylyne transition metal complexes and related metallogermylenes are reported. The reaction of Na[M(η5-C5H5)(CO)3] (M = Cr, or...

  报道了几种间三联苯稳定的锗炔过渡金属配合物和相关金属二甲苯的合成和表征。Na[M(η5-C5H5)(CO)3] (M = Cr, or...
• Braunstein, Pierre; De Jesús, Ernesto; Dedieu, Alain, Inorganic Chemistry, 1992, vol. 31, # 3, p. 399 - 410
  作者：Braunstein, Pierre、De Jesús, Ernesto、Dedieu, Alain、Lanfranchi, Maurizio、Tiripicchio, Antonio

  DOI：——

  日期：——
• Bender, Robert; Braunstein, Pierre; Jud, Jean-Marc, Inorganic Chemistry, 1984, vol. 23, # 26, p. 4489 - 4502
  作者：Bender, Robert、Braunstein, Pierre、Jud, Jean-Marc、Dusausoy, Yves

  DOI：——

  日期：——
• Synthesis and Characterization of the Metalloplumbylenes (η⁵-C₅H₅)(CO)₃M-P̈b-C₆H₃-2,6-Trip₂ (M = Cr, Mo, or W; Trip = −C₆H₂-2,4,6-i-Pr₃)
  作者：Lihung Pu、Philip P. Power、Imke Boltes、Regine Herbst-Irmer

  DOI：10.1021/om990774s

  日期：2000.2.1

  The reaction of Pb(Br)C6H3-2,6-Trip(2) (Trip = C6H2-2,4,6-i-Pr-3), generated in situ, with the salts Na[M(eta(5)-C5H5)(CO)(3)]. DME (M = Cr, Mo, or W; DME = 1,2-dimethoxyethane) affords the novel green, crystalline metalloplumbylenes (eta(5)-C5H5)(CO)(3)M-Pb-C6H3-2,6 -Trip(2) (M = Cr, 1; Mo, 2; W, 3) in moderate yield. The compounds were characterized spectroscopically (H-1, C-13, and Pb-207 NMR, IR, and UV-vis) and by combustion analysis. In addition the X-ray crystal structures of 1-3 were determined. The compounds feature strongly bent geometries at lead (M-Pb-C = 108.6(2)-113.58(9)degrees) and relatively long M-Pb distances (2.9092(9) Angstrom, Cr; 2.9845(7) Angstrom, Mo; 2.9809(10) Angstrom, 3.0055(6) Angstrom W), which are consistent with single M-Pb bonding. The stability of the complexes, which melt with decomposition in the range 210-226 degrees C, is attributed to steric protection of the metal centers by the very large -C6H3-2,6-Trip(2) substituent. The compounds are the first examples of metalloplumbylenes that feature a bent two-coordinate lead geometry.