1,1'-bis[4,4'-hexadecanamido-N-phenyloxybenzimine]ferrocene | 947489-00-1

• 英文名称: 1,1'-bis[4,4'-hexadecanamido-N-phenyloxybenzimine]ferrocene
• CAS: 947489-00-1
• 化学式: C₆₈H₉₀FeN₄O₄
• 分子量: 1083.33
• InChiKey: LSSXBOGWWOJIAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-(4-aminophenyloxy)hexadecanamide 、 1,1'-二茂铁二甲醛 在 盐酸 作用下， 以 乙醇 为溶剂， 以86%的产率得到1,1'-bis[4,4'-hexadecanamido-N-phenyloxybenzimine]ferrocene
  参考文献：
  名称：

  Synthesis and physico-analytical studies of some novel ferrocenyl Schiff base derivatives

  摘要：

  A series of ferrocenyl Schiff base derivatives was synthesized by condensation reactions of 1,1'-ferrocenedicarboxaldehyde and aromatic amines containing long chain alkyl groups as free ends which were characterized by their physical properties, elemental, FTIR, H-1 NMR, C-13 NMR spectral and thermal analysis. The thermal behaviour of the synthesized compounds was studied by differential scanning calorimetry (DSC) which revealed that these compounds may exhibit mesomorphic properties. The DSC results of aromatic amines and ferrocenyl Schiff bases were compared to study the effects of structure, i.e. rigid core and terminal chain length, on the phase transition behaviour. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.03.034