[copper(II)(N,N'-propylene-bis(3-methoxysalicylideneimine(-2H))sodium(I)(azido)(methanol)] | 1388725-11-8

• 英文名称: [copper(II)(N,N'-propylene-bis(3-methoxysalicylideneimine(-2H))sodium(I)(azido)(methanol)]
• CAS: 1388725-11-8
• 化学式: C₂₀H₂₄CuN₅NaO₅
• 分子量: 500.977
• InChiKey: AHHMWUGEBPKLJD-WVAQYUJYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  甲醇 、 N,N'-bis(3-methoxysalicylidene)-1,3-propanediamine 、 copper(II) acetate monohydrate 、 sodium azide 以 甲醇 、 水 为溶剂， 以74%的产率得到[copper(II)(N,N'-propylene-bis(3-methoxysalicylideneimine(-2H))sodium(I)(azido)(methanol)]
  参考文献：
  名称：

  Anion mediated diversity in the H-bonded assembly of a series of heteronuclear copper(II)/sodium(I) compounds

  摘要：

  Three heteronuclear Cu(II)/Na(I) compounds, [Cu(vanpn)Na(NO3)(H2O)] (1), [Cu(vanpn)Na(N-3)(CH3OH)] (2) and [Cu(vanpn)Na(NCS)(H2O)] (3) where H(2)vanpn = N,N'-(1,3-propylene)-bis(3-methoxysalicylideneimine), a well known compartmental Schiff base ligand, have been prepared and characterized by elemental analysis, IR and UV-Vis spectroscopy and single crystal X-ray diffraction studies. Compound 1 crystallises in monoclinic space group P2(1)/n, compound 2 in triclinic P (1) over bar and compound 3 in orthorhombic space group Pbca. In all the compounds, Cu atoms assume distorted square planar geometries whereas Na atoms exhibit distorted octahedral geometry. In compound 1, the nitrate ion is coordinated as a chelating ligand and essentially both the O atoms of the nitrate occupy one axial site. Variation of the counter anions leads to considerable change in the H-bonded supramolecular structures of the compounds. Compound 1 forms a dimer, compound 2 constitutes a chain and compound 3 forms a helix. Electrochemical electron transfer study reveals Cu(II) Cu(I) reduction in acetonitrile solution. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.03.044