[(diethylamino)bis(trimethylsilyl)silyl]hafnocene chloride | 1135185-13-5

• 英文名称: [(diethylamino)bis(trimethylsilyl)silyl]hafnocene chloride
• CAS: 1135185-13-5
• 化学式: C₂₀H₃₈ClHfNSi₃
• 分子量: 590.728
• InChiKey: DXYPFRKYRXSKRU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(diethylamino)bis(trimethylsilyl)silyl]hafnocene chloride 、 2,6-二甲基苯基异腈 以 甲苯 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Preparation, Structure and Reactivity of Et ₂ N(Me ₃ Si) ₂ SiK

  摘要：

  AbstractReaction of Et2NSi(SiMe3)3 with potassium tert‐butoxide gives the silylenoid Et2N(Me3Si)2SiK. Structural characterisation and reactivity of this compound was studied. It was found that while Et2N(Me3Si)2SiK exhibits the typical NMR spectroscopic properties for a silylenoid species it does not undergo self‐condensation under ambient conditions. Its reaction with zirconocene and hafnocene dichlorides gave the expected silyl metallocene chloride. However, there seems to be no strong interaction between the amino nitrogen atom and the group‐4 metal. Besides the synthesis of Et2N(Me3Si)2SiK also the preparation of the related silylenoid compound (Et2N)2(Me3Si)SiK and was accomplished. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

  DOI：

  10.1002/ejic.200701143
• 作为产物：
  描述：

  二氯二茂铪 、 (diethylamino)bis(trimethylsilyl)silyl potassium 以 甲苯 、 正戊烷 为溶剂， 以89%的产率得到[(diethylamino)bis(trimethylsilyl)silyl]hafnocene chloride
  参考文献：
  名称：

  Preparation, Structure and Reactivity of Et ₂ N(Me ₃ Si) ₂ SiK

  摘要：

  AbstractReaction of Et2NSi(SiMe3)3 with potassium tert‐butoxide gives the silylenoid Et2N(Me3Si)2SiK. Structural characterisation and reactivity of this compound was studied. It was found that while Et2N(Me3Si)2SiK exhibits the typical NMR spectroscopic properties for a silylenoid species it does not undergo self‐condensation under ambient conditions. Its reaction with zirconocene and hafnocene dichlorides gave the expected silyl metallocene chloride. However, there seems to be no strong interaction between the amino nitrogen atom and the group‐4 metal. Besides the synthesis of Et2N(Me3Si)2SiK also the preparation of the related silylenoid compound (Et2N)2(Me3Si)SiK and was accomplished. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

  DOI：

  10.1002/ejic.200701143