1-HC.ident.C-3,5-[Cl(CO)(PPh3)2(PMe3)OsCH=CH]2C6H3 | 847749-54-6

• 英文名称: 1-HC.ident.C-3,5-[Cl(CO)(PPh3)2(PMe3)OsCH=CH]2C6H3
• CAS: 847749-54-6
• 化学式: C₉₂H₈₆Cl₂O₂Os₂P₆
• 分子量: 1860.84
• InChiKey: QTQICCFUBLPHRM-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  hydridocarbonylchlorotris(triphenylphosphine)osmium(II) 、 1-HC.ident.C-3,5-[Cl(CO)(PPh3)2(PMe3)OsCH=CH]2C6H3 以 not given 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of Trimetallic Ruthenium and Bimetallic Osmium Complexes with Metal−Vinyl Linkages

  摘要：

  Treatment of RuHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3, which reacts with PMe3 to give 1,3,5-[Cl(CO)(PMe3)(3)RuCH=CH](3)C6H3. 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)(2)RuCH=CH](3)C6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh3)(3) with ArCdropCH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3)(3). Reaction of OsHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HCdropC-3,5-[Cl(CO)(PPh3)(3)OsCH=CH](2)C6H3, which reacts with PMe3 to give 1-HCdropC-3,5-[OsCl(CO)(PPh3)(2)(PMe3)OsCH=CH](2)C6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.

  DOI：

  10.1021/om0496939
• 作为产物：
  描述：

  1-HC.ident.C-3,5-[Cl(CO)(PPh3)3OsCH=CH]2C6H3 、 三甲基膦 以 四氢呋喃 为溶剂， 以88%的产率得到1-HC.ident.C-3,5-[Cl(CO)(PPh3)2(PMe3)OsCH=CH]2C6H3
  参考文献：
  名称：

  Synthesis and Characterization of Trimetallic Ruthenium and Bimetallic Osmium Complexes with Metal−Vinyl Linkages

  摘要：

  Treatment of RuHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the trimetallic complex 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3, which reacts with PMe3 to give 1,3,5-[Cl(CO)(PMe3)(3)RuCH=CH](3)C6H3. 1,3,5-[Cl(CO)(PPh3)(2)RuCH=CH](3)C6H3 also reacts with pyridine (Py) and 4-phenylpyridine (PhPy) to give 1,3,5-[Cl(CO)(L)(PPh3)(2)RuCH=CH](3)C6H3 (L = Py, PhPy). Reactions of OsHCl(CO)(PPh3)(3) with ArCdropCH (Ar = Ph, p-tolyl) produce the six-coordinated insertion products OsCl(CH=CHAr)(CO)(PPh3)(3). Reaction of OsHCl(CO)(PPh3)(3) with 1,3,5-triethynylbenzene produces the bimetallic complex 1-HCdropC-3,5-[Cl(CO)(PPh3)(3)OsCH=CH](2)C6H3, which reacts with PMe3 to give 1-HCdropC-3,5-[OsCl(CO)(PPh3)(2)(PMe3)OsCH=CH](2)C6H3. The electrochemical and second-order NLO properties of some of the new complexes have been investigated.

  DOI：

  10.1021/om0496939