(η2,η2-cycloocta-1,5-diene)bis(phenyltriazenide)benzene-platinum(II) | 874826-68-3

• 英文名称: (η2,η2-cycloocta-1,5-diene)bis(phenyltriazenide)benzene-platinum(II)
• CAS: 874826-68-3
• 化学式: C₂₆H₂₆N₆Pt
• 分子量: 617.613
• InChiKey: QVECBXJSBHNUJA-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 1,2-bis(phenyltriazeno)benzene 在 Na 、 AgNO₃ 作用下， 以 四氢呋喃 、 乙腈 为溶剂， 以89%的产率得到(η2,η2-cycloocta-1,5-diene)bis(phenyltriazenide)benzene-platinum(II)
  参考文献：
  名称：

  Stabilization of the (η4-COD)Pt-fragment (COD=η2,η2-cyclo-octa-1,5-diene) by a bistriazenide: Synthesis and X-ray structural characterization of [(η4-COD)Pt(NNN-Ph)2C6H4], a neutral 1,2-bis(phenyltriazenido)benzene complex of platinum(II)

  摘要：

  After exchange of Cl against NO3 by reaction with AgNO3 [(COD)PtCl2] reacts with the sodium salt of 1,2-bis(phenyltriazene)benzene to give [(eta(4)-COD)Pt(NNN-Ph)(2)C6H4], the first example of a pi-fragment of platinum(II) stabilized by two symmetrical triazenide chains. The new complex belongs to the monoclinic space group C2/c and corroborates the ability of the (COD)Pt fragment to be stabilized by bidentate ligands. The odd flying dragon structure of the title compound retains the C-2v symmetry of the free anion 1,2-bis(phenyltriazenide)benzene. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.09.018