([Ag(1,3-bis(methylthio)propane)2](tetrafluoroborate)).infin. | 165259-29-0

• 英文名称: ([Ag(1,3-bis(methylthio)propane)2](tetrafluoroborate)).infin.
• CAS: 165259-29-0
• 化学式: Ag*BF₄*C₅H₁₂S₂
• 分子量: 330.955
• InChiKey: YKUOOGVNXOISHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-二硫代庚烷 、 silver tetrafluoroborate 以 丙酮 为溶剂， 以75%的产率得到([Ag(1,3-bis(methylthio)propane)2](tetrafluoroborate)).infin.
  参考文献：
  名称：

  Unique structural features in silver(I) dithioether complexes: the single-crystal structures of [Ag_n(PhSCH₂CH₂CH₂SPh)_2n](BF₄)_n·0.5nH₂O and [Ag_n(MeSCH₂CH₂CH₂SMe)_n](BF₄)_n

  摘要：

  Agn(PhSCH2CH2CH2SPh)2n]n+的X射线结构显示了一个由四面体AgI原子组成的无限阵列，通过四个不同的PhSCH2CH2CH2SPh配体的一个S-载体配位、而[Agn(MeSCH2CH2CH2SMe)n]n+ 是一种链状聚合物，涉及三方（μ2-S）2、S 键合，其中一个 S 键合体桥接两个相邻的 AgI 中心，而二硫醚配体的另一个 S 键合体则不桥接。

  DOI：

  10.1039/c39950001277

文献信息

• Homoleptic silver(I) complexes with dithio-, diseleno- and ditelluro-ethers: synthesis, structures and multinuclear nuclear magnetic resonance studies
  作者：Jane R. Black、Neil R. Champness、William Levason、Gillian Reid

  DOI：10.1039/dt9950003439

  日期：——

  Homoleptic silver(I) complexes [Ag(L–L)2]BF4L–L = RE(CH2)nER [R = Ph or Me, n= 2 or 3 (E = S or Se), n= 3 (E = Te)]} have been prepared and characterised by analysis, FAB mass spectrometry, and multinuclear NMR spectroscopy (1H, 77Se, 125Te and 109Ag). Variable-temperature NMR studies have been used to probe various exchange processes occurring in solution. The crystal structure of the tetrafluoroborate

  同质银（I）配合物[Ag（L–L）2 ] BF 4 L–L = RE（CH 2）n ER [R = Ph或Me，n = 2或3（E = S或SE），n＝ 3（E ＝ Te）]}已经制备并通过分析，FAB质谱和多核NMR光谱法（1 H，77 SE，125 Te和109 Ag）表征。可变温度NMR研究已用于探测溶液中发生的各种交换过程。将[Ag（MeSECH的四氟硼酸盐的晶体结构2 CH 2 SEME）2 ] +图1显示了二齿醚配体以双齿方式与形成扭曲的四面体1+阳离子的Ag I离子配位。相反，在[Ag n（PhSECH 2 CH 2 CH 2 SEPh）2 n ] n +的四氟硼酸盐的晶体结构中，阳离子是一个无限的网络，包含通过四个不同的二硒醚中的一个SE原子四面连接的Ag原子。配体，这些配体又与相邻的Ag原子连接。
• Influence of the counteranion on silver(I)–dithioether coordination polymers
  作者：Mohamed Osman Awaleh、Francois Brisse、Youssouf Djibril Soubaneh、Thierry Maris

  DOI：10.1016/j.poly.2010.08.013

  日期：2010.10

  In order to rationalize the effect of the size and coordinating ability of counteranions upon the structure of Ag(I)-dithioether coordination polymers, a series of such polymers has been synthesized by the combination of the 1,3-bis(methylthio)propane building block and AgX silver salts (X = CIO4- (1), BF4- (2), CF3SO3- (3), SbF6- (4), C6H5COO- (5), CF3COO- (6), CF3CF2CF2COO- (7) and -OOCCF2CF2COO- (8)). Except in two cases, all complexes form 1D-coordination polymers.Coordination polymers 1 and 2 are isostructural with tubular cationic chains. Coordination polymers 3 and 4 have similar cationic chains, except that 3 incorporates in its crystal structure an additional acetone molecule. In 5, neighboring [(C6H5COO)Ag](2) dimers are linked via the oxygen atom of the benzoate group to build up a [(C6H5COO)Ag](infinity) 1D-dimensional coordination polymer. The chains are further interconnected by ligand molecules that bind two consecutive silver atoms.The short Ag center dot center dot center dot Ag contacts (2.920(1)-3.363(1)angstrom) in 5,7 and 8 may indicate the presence of weak silver-silver interactions. Coordination polymer 6 forms a neutral 2D-coordination network, in which the trifluoroacetate anions complete the coordination sphere of the metal center. In 7, the neutral 1D-coordination polymer is made up through unsupported silver-silver interactions. The structure of 8 is made up of the same chains of 7 that are connected to each other by the tetrafluorosuccinate anions, resulting in a 2D-supramolecular network. The stoichiometries of polymers 1 and 2 were found to depend on the metal-to-ligand ratio of the starting materials, contrary to the stoichiometries of the other coordination networks 3-8. (C) 2010 Elsevier Ltd. All rights reserved.