([Ag(1,3-bis(methylthio)propane)](hexafluoroantimonate)).infin. | 1255705-62-4

• 英文名称: ([Ag(1,3-bis(methylthio)propane)](hexafluoroantimonate)).infin.
• CAS: 1255705-62-4
• 化学式: Ag*C₅H₁₂S₂*F₆Sb
• 分子量: 479.891
• InChiKey: ROGOVMHNJAOJGE-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver hexafluoroantimonate 、 2,6-二硫代庚烷 以 乙醚 、 丙酮 为溶剂， 以78%的产率得到([Ag(1,3-bis(methylthio)propane)](hexafluoroantimonate)).infin.
  参考文献：
  名称：

  Influence of the counteranion on silver(I)–dithioether coordination polymers

  摘要：

  In order to rationalize the effect of the size and coordinating ability of counteranions upon the structure of Ag(I)-dithioether coordination polymers, a series of such polymers has been synthesized by the combination of the 1,3-bis(methylthio)propane building block and AgX silver salts (X = CIO4- (1), BF4- (2), CF3SO3- (3), SbF6- (4), C6H5COO- (5), CF3COO- (6), CF3CF2CF2COO- (7) and -OOCCF2CF2COO- (8)). Except in two cases, all complexes form 1D-coordination polymers.Coordination polymers 1 and 2 are isostructural with tubular cationic chains. Coordination polymers 3 and 4 have similar cationic chains, except that 3 incorporates in its crystal structure an additional acetone molecule. In 5, neighboring [(C6H5COO)Ag](2) dimers are linked via the oxygen atom of the benzoate group to build up a [(C6H5COO)Ag](infinity) 1D-dimensional coordination polymer. The chains are further interconnected by ligand molecules that bind two consecutive silver atoms.The short Ag center dot center dot center dot Ag contacts (2.920(1)-3.363(1)angstrom) in 5,7 and 8 may indicate the presence of weak silver-silver interactions. Coordination polymer 6 forms a neutral 2D-coordination network, in which the trifluoroacetate anions complete the coordination sphere of the metal center. In 7, the neutral 1D-coordination polymer is made up through unsupported silver-silver interactions. The structure of 8 is made up of the same chains of 7 that are connected to each other by the tetrafluorosuccinate anions, resulting in a 2D-supramolecular network. The stoichiometries of polymers 1 and 2 were found to depend on the metal-to-ligand ratio of the starting materials, contrary to the stoichiometries of the other coordination networks 3-8. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.08.013