[Pd(SC6H4-4-F)2(1,1'-bis(diphenylphosphino)ferrocene)] | 745013-69-8

• 英文名称: [Pd(SC6H4-4-F)2(1,1'-bis(diphenylphosphino)ferrocene)]
• CAS: 745013-69-8
• 化学式: C₄₆H₃₆F₂FeP₂PdS₂
• 分子量: 915.135
• InChiKey: PGISAEMPTUQPLF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 lead 4-fluorobenzenethiolate 以 二氯甲烷 、 丙酮 为溶剂， 以93.5%的产率得到[Pd(SC6H4-4-F)2(1,1'-bis(diphenylphosphino)ferrocene)]
  参考文献：
  名称：

  [1,1′-Bis(diphenylphosphino)ferrocene]palladium(II) complexes with fluorinated benzenethiolate ligands: examination of the electronic effects in the solid state, solution and in the Pd-catalyzed Heck reaction with the catalytic system [Pd(dppf)(SRF)2]

  摘要：

  A series of palladium thiolate complexes of the type [Pd(dppf)(SRF)(2)] have been synthesized in good yields by metathetical reactions of [Pd(dppf)Cl-2] with [Pb(SRF)(2)], (SRF = -SC6F5, -SC6F4-4-H, -SC6H4-2-CF3, -SC6H4-4-F, -SC6H4-3-F) and their crystal structures determined. The effect of the different thiolates in the structural properties of the complexes both in the solid state and in solution have been analyzed. Heck coupling reactions were carried out using the complexes [Pd(dppf)(SRF)(2)], SRF = -SC6F5 (1), -SC6F4-4-H (2), -SC6H4-2-CF3 (3), -SC6H4-4-F (4), -SC6H4-3-F (5) as catalysts in order to examine both the effect of the thiolates and the P-Pd-P bite angles in the reaction of bromobenzene and styrene. The results obtained indicate that electron-withdrawing substituents may favor higher yields in the Pd catalyzed Heck reaction using [Pd(dppf)(SRF)(2)] as catalysts. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.04.035