| 89578-88-1

• CAS: 89578-88-1
• 化学式: C₅MoO₅
• 分子量: 235.992
• InChiKey: IZPMSXOZAHCRGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 氧气 作用下， 以 gaseous matrix 为溶剂， 生成 molybdenum(VI) oxide 、 molybdenum(VI) oxide dihydrate 、 Molybdenum;pentahydrate 、
  参考文献：
  名称：

  过渡金属羰基阴离子与双氧在气相中的反应

  摘要：

  反应不包括新加之新贵金属氧化物的例子 d'anions d'oxydes metalliques produits 温度正常。Nature Radialaire de l'oxydation primaire

  DOI：

  10.1021/ja00321a051
• 作为产物：
  描述：

  molybdenum hexacarbonyl 生成 、 一氧化碳
  参考文献：
  名称：

  Dissociative electron attachment reactions of transition metal carbonyls and their apparent influence on the thermalization of electrons by CO₂

  摘要：

  Dissociative electron attachment rates are measured for the transition metal carbonyls V(CO)6, Cr(CO)6, Fe(CO)5, Ni(CO)4, Mo(CO)6, and W(CO)6. Rates are measured as a function of the pressure of CO2 added to relax epithermal electrons. Derived thermal rate constants for the formation of M(CO)−n−1 from M(CO)n are 0.6, 3.0, 2.0, 2.0, 1.3, and 1.2×10−7 cm3 molecule−1 s−1, respectively. The differences in these rate constants may be attributed to the different stabilities of the molecular anion with regard to dissociation versus autodetachment. The measured rate of thermalization of electrons by CO2 varies with the metal carbonyl used and depends on the variation of the dissociative electron capture cross section with electron energy. Each system is thus tightly coupled in that the electron energy distribution is determined not only by collisional processes involving CO2 but varies as well with the energy dependent depletion of the distribution by reactant species.

  DOI：

  10.1063/1.443389