[5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin]iron(III) chloride | 144810-55-9

• 英文名称: [5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin]iron(III) chloride
• 英文别名: FeTPPCl(OH)；FeCl-[5-(4-hydroxylphenyl)-10,15,20-triphenylporphyrin]
• CAS: 144810-55-9
• 化学式: C₄₄H₂₈ClFeN₄O
• 分子量: 720.033
• InChiKey: ZZZWJPQJKHAPJB-YKKPBKTHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  1,8,15,22-tetranitrophthalocyanatozinc (II) 、 [5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin]iron(III) chloride 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 6.0h， 以55%的产率得到ZnPC-(FeTPP)4
  参考文献：
  名称：

  Synthesis and characterization of three covalently linked porphyrin-phthalocyanine pentamers with nucleophilic substitution

  摘要：

  In this paper the synthetic methods of three covalently linked porphyrin-phthalocyanine heteropentamers, containing four units of porphyrin linked to a central phthalocyanine (Mpor-LPc; M = 2H, Fe, L = Zn, Fe), are described. The synthetic strategy is on the basis of nucleophilic substitution reactions between [1,8,15,22-tetra nitro phthalocyanines] and [5-(4-hydroxy phenyl)-10,15,20-triphenyl porphyrins] as the phenolic alcohols. Porphyrins are linked with oxygen as spacer through meso position of phenyl group to phthalocyanines. These macromolecules were characterized by H-1 NMR, UV-Vis, IR, fluorescence and mass spectroscopy. The electronic absorption spectrums of the hetero-dyad systems changed significantly upon coupling and showed a great red shift in the phthalocyanine Q-bands. These changes confirm the electron-donating effects of the porphyrin units and the extension of conjugated pi-systems. The emission spectra of the products supports intramolecular energy and charge transfer between the sub-units. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.03.022
• 作为产物：
  描述：

  5-(4'-hydroxyphenyl)-10,15,20-triphenylporphyrin 在 iron(II) chloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以87%的产率得到[5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin]iron(III) chloride
  参考文献：
  名称：

  Synthesis and characterization of three covalently linked porphyrin-phthalocyanine pentamers with nucleophilic substitution

  摘要：

  In this paper the synthetic methods of three covalently linked porphyrin-phthalocyanine heteropentamers, containing four units of porphyrin linked to a central phthalocyanine (Mpor-LPc; M = 2H, Fe, L = Zn, Fe), are described. The synthetic strategy is on the basis of nucleophilic substitution reactions between [1,8,15,22-tetra nitro phthalocyanines] and [5-(4-hydroxy phenyl)-10,15,20-triphenyl porphyrins] as the phenolic alcohols. Porphyrins are linked with oxygen as spacer through meso position of phenyl group to phthalocyanines. These macromolecules were characterized by H-1 NMR, UV-Vis, IR, fluorescence and mass spectroscopy. The electronic absorption spectrums of the hetero-dyad systems changed significantly upon coupling and showed a great red shift in the phthalocyanine Q-bands. These changes confirm the electron-donating effects of the porphyrin units and the extension of conjugated pi-systems. The emission spectra of the products supports intramolecular energy and charge transfer between the sub-units. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.03.022