| 1392295-15-6

• CAS: 1392295-15-6
• 化学式: C₃₀H₃₀BBrF₂N₂O₄
• 分子量: 611.291
• InChiKey: AQRJJPNIWIHWKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4,4'-联吡啶 、 、 溴甲苯 在 potassium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 168.0h， 以101 mg的产率得到benzylviologen-BODIPY dyad
  参考文献：
  名称：

  Fluorescence-On Response via CB7 Binding to Viologen–Dye Pseudorotaxanes

  摘要：

  Fluorescence-on sensors typically rely on disrupting photoinduced electron transfer quenching of the excited state through binding the electron donor. To provide a more general fluorescence-on signaling unit, a quencher-fluorophore dyad has been developed in which quenching by electron transfer to a tethered viologen acceptor can be disrupted through complexation of the viologen by cucurbit[7]uril (CB7). Dyads of benzyl viologen-rhodamine B or a BODIPY fluorophore gave upon CB7 complexation 14- and 30-fold fluorescence enhancement, respectively.

  DOI：

  10.1021/ol300963c
• 作为产物：
  描述：

  2,4-二甲基吡咯 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 80.5h， 生成
  参考文献：
  名称：

  Fluorescence-On Response via CB7 Binding to Viologen–Dye Pseudorotaxanes

  摘要：

  Fluorescence-on sensors typically rely on disrupting photoinduced electron transfer quenching of the excited state through binding the electron donor. To provide a more general fluorescence-on signaling unit, a quencher-fluorophore dyad has been developed in which quenching by electron transfer to a tethered viologen acceptor can be disrupted through complexation of the viologen by cucurbit[7]uril (CB7). Dyads of benzyl viologen-rhodamine B or a BODIPY fluorophore gave upon CB7 complexation 14- and 30-fold fluorescence enhancement, respectively.

  DOI：

  10.1021/ol300963c