[(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2O | 1280103-59-4

• 英文名称: [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2O
• CAS: 1280103-59-4
• 化学式: C₅₈H₈₆Ge₂N₄O
• 分子量: 1000.53
• InChiKey: ZIPKCNOQXOPSPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium oxide 、 [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2GeCl] 以 四氢呋喃 为溶剂， 以0%的产率得到[(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2O
  参考文献：
  名称：

  Synthesis and Characterization of an Amidinate-Stabilized Bisgermylene Oxide and Sulfide

  摘要：

  The synthesis and characterization of the amidinate-stabilized bisgermylene oxide and sulfide [(LGe)-Ge-2-E-GeL2] (E = 0 (2), S (3); L-2 = (BuC)-C-t(NAr)(2), Ar = 2,6-(Pr2C6H3)-C-i) are described. Compound 2 was prepared by the reaction of two equivalents of [L2GeCl] (1) with Me3NO and two equivalents of KC8 in THF. It is proposed that the reaction proceeds through an [(LGe1)-Ge-2] intermediate, which then reacts with Me3NO to form 2. Similarly, the reaction of two equivalents of 1 with elemental sulfur and two equivalents of KC8 in THE afforded 3. Compounds 2 and 3 have been characterized by NMR spectroscopy and X-ray crystallography.

  DOI：

  10.1021/om101194f