[Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)] | 1420831-79-3

• 英文名称: [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)]
• CAS: 1420831-79-3
• 化学式: C₄₄H₄₀IrP₃
• 分子量: 853.943
• InChiKey: PGEMYZPSERYMBX-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)] 、 碘甲烷 以 四氢呋喃 为溶剂， 反应 2.0h， 以100%的产率得到[Ir(MeP(C₆H₄PPh₂)₂)(COD)]I
  参考文献：
  名称：

  Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

  摘要：

  The first example of an iridium(I) species bearing a terminal phosphido (PR2-) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium(I)-gold(I) dinuclear species.

  DOI：

  10.1021/ic302301h
• 作为产物：
  描述：

  [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphine)(COD)][PF₆] 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 生成 [Ir(fac-bis[(2-diphenylphosphino)phenyl]phosphide)(COD)]
  参考文献：
  名称：

  Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand

  摘要：

  The first example of an iridium(I) species bearing a terminal phosphido (PR2-) ligand is reported. This stable compound shows well-behaved reactivity toward various electrophiles, owing to its exposed phosphorus lone pair, allowing reversible protonation, selective alkylation, isolation of a phosphidoborane of iridium, and generation of a phosphido-bridged iridium(I)-gold(I) dinuclear species.

  DOI：

  10.1021/ic302301h